常压等离子沉积法制备TiO2薄膜在染料敏化太阳能电池中的应用研究

W. Chou, Wen-Jen Liu
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引用次数: 5

摘要

采用自主研发的低成本、操作方便的大气等离子体系统进行氧化钛薄膜沉积,并对DSSCs的应用进行了评价。采用无机前驱体(钛四异丙醇,TTIP)制备TiO2薄膜,研究了沉积时间对薄膜性能和微观结构的影响。此外,该系统还用于研究高比表面积和排列良好的TiO2纳米枝晶(TNDs)薄膜作为DSSCs光阳极的核心沉积技术。目前,在模拟AM1.5太阳光照(100 mWcm-2)下,采用N719染料和碘离子电解质制备的超高沉积速率~2μm/min的TNDs薄膜的最佳光转换效率为12.08%。在本研究中,采用最佳工艺参数合成的薄膜具有高比表面积和排列良好的TNDs形貌,可以显著提高光转换效率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of dye sensitized solar cell application of TiO2 films by atmospheric pressure plasma deposition method
Self-developed, low-cost and convenient-operation atmospheric plasma system was used to perform titanium oxide films deposition, and the application of DSSCs was also assessed. Inorganic precursor (titanium tetraisopropoxide, TTIP) was used to form TiO2 films, and the effects of the deposition times on the characteristic and microstructure had been investigated. Moreover, the system was used to study the core deposition technology of high specific surface area and well-aligned TiO2 nano-dendrites (TNDs) films served as photo-anode for the DSSCs applications. Up to date, the optimal TNDs films with an extra high deposition rate of ~2μm/min revealed the best photo-conversion efficiency of 12.08% for adopting N719 dye and iodine ion electrolyte, under illumination of simulated AM1.5 solar light (100 mWcm-2). In this study, the films synthesized using optimum process parameters with a high specific surface area and well-aligned TNDs morphology can significantly improve the photo-conversion efficiency.
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