Sn-Ag-Cu/Cu界面金属间化合物层在焊接过程中的生长行为

D.Q. Yu, J.H. Wang, L. Wang
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引用次数: 1

摘要

研究了Sn-3.5Ag、Sn-3.5Ag-0.7Cu、Sn-3.5Ag-1.7Cu和Sn-0.5Ag-4Cu无铅钎料合金在Cu基体上的熔化性能及其金属间化合物(IMC)层的生长行为。结果表明:Sn-3.5Ag、Sn-3.5Ag-0.7Cu和Sn-3.5Ag-1.7Cu钎料熔点基本一致,均为一个共晶峰,而Sn-0.5Ag- 4cu钎料熔点分别为/spl β / | Cu/sub 6/Sn/sub 5/ + Ag/sub 3/Sn /spl rarr/ L和/spl β / + Cu/sub 6/Sn/sub 5/ /spl rarr/ L两个吸热峰。随着Sn-3.5Ag、Sn-3.5Ag-0.7Cu和Sn-3.5Ag-1.7Cu钎料中Cu含量的增加,IMC的溶解速率降低,导致IMC厚度减小。当焊接时间较短时,Sn-0.5Ag-4Cu的IMC厚度很薄。然而,随着焊接时间的增加,厚度很快变厚,这是由于液态焊料中Cu/sub 6/Sn/sub 5/的沉淀作用导致的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The growth behavior of intermetallic compound layer of Sn-Ag-Cu/Cu interface during soldering
The melting properties of Sn-3.5Ag, Sn-3.5Ag-0.7Cu, Sn-3.5Ag-1.7Cu and Sn-0.5Ag-4Cu lead-free solder alloys and the growth behavior of the intermetallic compound (IMC) layer of these solders on a Cu substrate during soldering are investigated. The results indicate that the melting points of Sn-3.5Ag, Sn-3.5Ag-0.7Cu and Sn-3.5Ag-1.7Cu solders are quite similar with one eutectic peak, while Sn-0.5Ag-4Cu solder has two endothermal peaks according to /spl beta/ | Cu/sub 6/Sn/sub 5/ + Ag/sub 3/Sn /spl rarr/ L and /spl beta/ + Cu/sub 6/Sn/sub 5/ /spl rarr/ L reactions, respectively. With the increasing Cu content in Sn-3.5Ag, Sn-3.5Ag-0.7Cu and Sn-3.5Ag-1.7Cu solders, the IMC thickness decreases due to the decrease of the dissolution rate of the IMC. The IMC thickness of Sn-0.5Ag-4Cu is quite thin when the soldering time is short. However, with increasing soldering time, the thickness turns thick very soon, which is led by the precipitation effect of the Cu/sub 6/Sn/sub 5/ in the liquid solder.
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