TiN/AlCu/TiN/sub / x/互连的耐EM能力增强

J. Byun, J. K. Kim, K. Rha, W. Kim
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摘要

只提供摘要形式。在亚微米器件中,TiN用作多层铝互连中的阻挡层(例如,TiN/Al/TiN)。反应溅射法制备的TiN层呈10 nm左右的柱状晶粒结构。在本研究中,我们重点研究了由TiN/sub x/形成TiN的另一种技术,并比较了使用TiN/sub x/和传统TiN的多层互连的电迁移(EM)耐久性。为了研究铝和TiN/sub x/层形成的TiN的结构,制备了如下样品。采用直流磁控溅射的方法,在氮气和氩气的混合气氛中(氮气的体积百分比固定为15%),在400 nm厚的氧化硅片上反应沉积了厚度为50 nm的TiN/sub x/薄膜。在600 /spl℃下RTA热处理20秒后,依次沉积Al-0.5%Cu膜(500 nm厚)和TiN膜(40 nm厚)。铝条宽度为0.4 /spl mu/m,长度为1400 /spl mu/m,在温度为400 /spl,温度为15% H/sub / 2/ N/sub / 2/ ambient条件下30min的条件下进行合金处理。最后,沉积了由CVD氮化物(1.2 /spl mu/m厚)和CVD氧化物(0.4 /spl mu/m厚)组成的钝化层。采用RBS、XRD、AES分析了RTA前后膜的性能。与使用传统TiN作为底层阻挡层(MTTF /spl sim/10/sup 2/ min)相比,这种互连显示出极高的电磁耐受性(MTTF /spl sim/10/sup 4/ min)。Al和TiN之间的晶体连续性抑制了Al原子的界面扩散和晶界扩散,从而提高了电磁耐久性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhanced EM endurance of TiN/AlCu/TiN/sub x/ interconnection
Summary form only given. In submicron devices, TiN is used as a barrier layer in multilayered aluminum interconnection (e.g., TiN/Al/TiN). The conventional TiN layer is formed by reactive sputtering, which shows a columnar grain structure about the size of 10 nm. In this study, we focused on another technique of forming TiN from TiN/sub x/, and compared the electromigration (EM) endurance of the multilayered interconnections using TiN/sub x/ and conventional TiN. In order to investigate the structural aspects of aluminum and the TiN formed from the TiN/sub x/ layer, the samples were prepared as follows. TiN/sub x/ film of 50 nm thickness was reactively deposited on the oxidized (400 nm thick) silicon wafer by using DC magnetron sputtering in a mixed gas atmosphere of argon and nitrogen, in which the volume percent of nitrogen was fixed at 15%. After thermal treatment at 600 /spl deg/C for 20 sec using RTA, Al-0.5%Cu film (500 nm thick) and TiN (40 nm thick) film were sequentially deposited. After patterning of aluminum stripes of 0.4 /spl mu/m width and 1400 /spl mu/m length, the samples were alloyed at 400 /spl deg/C, 30 min in 15% H/sub 2//N/sub 2/ ambient. Finally, a passivation layer consisting of CVD nitride (1.2 /spl mu/m thick) and CVD oxide (0.4 /spl mu/m thick) was deposited. The film properties before and after RTA were analyzed using RBS, XRD, and AES. Such an interconnection showed extremely high EM endurance (MTTF /spl sim/ 10/sup 4/ min) in comparison with that using the conventional TiN as an underlying barrier layer (MTTF /spl sim/10/sup 2/ min). It is suggested that the crystal continuity between the Al and the TiN suppresses interface and grain boundary diffusion of Al atoms to improve the EM endurance.
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