Dissociative electron attachment to 1- and 9-chloroanthracene in the gas phase

Abstract

Dissociative electron attachment (DEA) to 1-chloroanthracene and 9-chloroanthracene was investigated under gas-phase conditions. In both compounds, the elimination of the chlorine anion is the dominant channel for the dissociation of molecular negative ions (NIs). The second most intense channel leads to the formation of molecular anions (Mˉ). The autodetachment lifetime of Mˉ was measured to be about 170 μs for both compounds. The widths of the Mˉ peaks indicate that molecular anions are formed via two resonances: at thermal electron energies and through a shape resonance at the energy of ∼0.5 eV. Adiabatic electron affinities were estimated in the framework of the simple Arrhenius model to be 0.86 eV for both molecules, the values being close to the theoretical predictions by DFT method of 0.90 eV and 0.93 eV for 1-chloroanthracene and 9-chloroanthracene respectively. Metastable negative ions are observed in the DEA spectra of both molecules, which testifies that the elimination of chlorine anions from molecular NIs appears on a time scale of several microseconds.