Scanning photoelectron spectromicroscopy: From static to operando studies of functional materials

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2023-05-01 DOI:10.1016/j.elspec.2023.147336

M. Amati , Toma Susi , P. Jovičević-Klug , M. Jovičević-Klug , Tomasz Kosmala , Gaetano Granozzi , Stefano Agnoli , Pengfei Yang , Yanfeng Zhang , Mattia Scardamaglia , L. Gregoratti

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引用次数: 0

Abstract

The scanning photoelectron microscope (SPEM), developed more than 30 years ago, has undergone numerous technical developments, providing an incredibly vast kind of feasible sample environments, which span from the traditional high spatial resolution core level based chemical analysis to insitu and operando complex experiments, including also electrochemical setups and operational electronic devices at various temperatures. Another important step ahead is overcoming the so-called pressure gap for operando studies, recently extended to near ambient values by building special environmental cells. Using recent results of conventional and unconventional experiments, obtained with SPEM at the ESCA Microscopy beamline at Elettra Sincrotrone Trieste the present review demonstrates the current potential of this type of photoelectron spectromicroscopy to explore the interfacial properties of functional materials with high spatial resolution.

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扫描光电子能谱显微镜：从静态到操作的功能材料研究

扫描光电子显微镜(SPEM)在30多年前发展起来，经历了许多技术发展，提供了一种令人难以置信的广泛可行的样品环境，从传统的高空间分辨率基于核心水平的化学分析到原位和操作复杂的实验，包括电化学设置和各种温度下的操作电子设备。另一个重要的进展是克服所谓的operando研究的压力差距，最近通过建造特殊的环境细胞扩展到接近环境值。利用最近在Elettra Sincrotrone Trieste的ESCA显微镜光束线上使用SPEM获得的常规和非常规实验结果，本文综述了这种类型的光电子能谱显微镜在探索高空间分辨率功能材料的界面特性方面的潜力。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.