Spinel-based electromagnetic wave absorbing materials: Multiscale design from crystal structure to morphology regulation

IF 10.6 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Xinglai Yuan, Hao Wu, Yuxin Ma, Wei Li, Hailong Wang, Pengpeng Liang, Gang Wang, Hongxia Li, Hongliang Xu, Rui Zhang, Bingbing Fan
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Abstract

The widespread application of electromagnetic wave technologies in telecommunications, healthcare, and defense has led to increasingly severe electromagnetic radiation pollution, driving an urgent demand for high-performance electromagnetic wave absorbing materials. Among various candidate systems, spinel-based absorbing materials stand out due to their exceptional compositional tunability, rich electromagnetic response mechanisms, and superior loss characteristics, making them a research hotspot in the field of electromagnetic functional materials. In this review, recent progress in spinel-based electromagnetic wave absorbing materials spanning from atomic-scale engineering to multiscale integration was systematically summarized. Particular emphasis is placed on entropy engineering-driven lattice distortion and defect synergistic effects, as well as on morphology engineering and heterogeneous composite strategies for constructing multiscale functional architectures and metamaterial-inspired systems. Furthermore, the fundamental structure-property relationships governing EMW attenuation are discussed, together with the current challenges and emerging opportunities in this rapidly evolving field. Finally, future research directions are also outlined to facilitate the rational design of next-generation spinel-based absorbers with enhanced efficiency and multifunctionality. This review provides a comprehensive framework for the design principles of spinel-based EMW absorbers and offers valuable insights to guide the rational development of next-generation high-performance electromagnetic functional materials.
尖晶石基电磁波吸收材料:从晶体结构到形态调节的多尺度设计
随着电磁波技术在通信、医疗、国防等领域的广泛应用,导致电磁辐射污染日益严重,对高性能电磁波吸收材料的需求日益迫切。在众多候选体系中,尖晶石基吸波材料以其优异的成分可调性、丰富的电磁响应机制和优越的损耗特性脱颖而出,成为电磁功能材料领域的研究热点。本文系统综述了尖晶石基电磁波吸收材料从原子尺度工程到多尺度集成的研究进展。特别强调熵工程驱动的晶格畸变和缺陷协同效应,以及用于构建多尺度功能架构和超材料启发系统的形态学工程和异质复合策略。此外,还讨论了控制EMW衰减的基本结构-性质关系,以及这个快速发展领域当前的挑战和新出现的机遇。最后,展望了未来的研究方向,以促进新一代高效、多功能尖晶石基吸收材料的合理设计。本文综述为尖晶石基EMW吸波材料的设计原理提供了一个全面的框架,为指导下一代高性能电磁功能材料的合理开发提供了有价值的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Materiomics
Journal of Materiomics Materials Science-Metals and Alloys
CiteScore
14.30
自引率
6.40%
发文量
331
审稿时长
37 days
期刊介绍: The Journal of Materiomics is a peer-reviewed open-access journal that aims to serve as a forum for the continuous dissemination of research within the field of materials science. It particularly emphasizes systematic studies on the relationships between composition, processing, structure, property, and performance of advanced materials. The journal is supported by the Chinese Ceramic Society and is indexed in SCIE and Scopus. It is commonly referred to as J Materiomics.
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