Sustainable Biodiesel Production From High-FFA Chicken Waste Oil: RSM-Based Optimization of Esterification and Transesterification Processes

IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED
Journal of the American Oil Chemists Society Pub Date : 2026-07-02 Epub Date: 2026-05-12 DOI:10.1002/aocs.70099
Shekhar Chauhan, Atanu Kumar Paul, Vaibhav V. Goud
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引用次数: 0

Abstract

Growing concerns over environmental impact and limited fossil fuel reserves have led to the urgent need for sustainable and renewable energy alternatives, such as biodiesel, to decrease pollution and ensure long-term energy security. This study focused on utilizing chicken waste oil, a cost-effective by-product of the food industry with high free fatty acid (FFA) content (> 25%), to produce biodiesel that aids waste management. A two-step process involving acid esterification followed by base transesterification was employed. Response surface methodology (RSM) was applied to optimize key process parameters with the aim of improving efficiency and reducing reactant usage. The esterification process reduced the acid value to 1.32 mg KOH g−1, making it optimum for the transesterification process. A maximum biodiesel yield of 98.9% was achieved with reduced reaction time and lower reactant consumption compared to conventional processes, enhancing the process's environmental sustainability and cost-effectiveness. The produced biodiesel exhibited favorable fuel properties, including density (at 20°C), viscosity, and calorific value, satisfying ASTM standards. Chicken waste oil, despite its high FFA content, demonstrates strong potential as a biodiesel feedstock, contributing to reduced CO2 emissions and supporting climate change mitigation.

Abstract Image

高游离脂肪酸鸡废油可持续生产生物柴油:基于rsm的酯化和酯交换工艺优化
对环境影响和有限的化石燃料储备的日益关注,导致迫切需要可持续和可再生能源替代品,如生物柴油,以减少污染和确保长期的能源安全。这项研究的重点是利用鸡废油,一种具有成本效益的食品工业副产品,具有高游离脂肪酸(FFA)含量(> 25%),生产有助于废物管理的生物柴油。采用了酸酯化和碱酯交换两步法。采用响应面法(RSM)对关键工艺参数进行优化,以提高效率,减少反应物用量。酯化过程使酸值降至1.32 mg KOH g−1,为酯交换过程的最佳条件。与传统工艺相比,在缩短反应时间和降低反应物消耗的情况下,生物柴油的最高产率达到98.9%,提高了该工艺的环境可持续性和成本效益。所生产的生物柴油表现出良好的燃料性能,包括密度(在20°C时)、粘度和热值,满足ASTM标准。尽管鸡废油的游离脂肪酸含量很高,但它作为生物柴油原料的潜力很大,有助于减少二氧化碳排放并支持减缓气候变化。
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来源期刊
CiteScore
4.10
自引率
5.00%
发文量
95
审稿时长
2.4 months
期刊介绍: The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate. JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of year­to­year, environmental, and/ or cultivar variations through use of appropriate statistical analyses.
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