Temperature-Modulated Nanoarchitectonics on the Electrochemical Performance of High Energy Supercapacitor Electrodes Derived From Mango Seeds

IF 1.9 4区 材料科学 Q3 Chemistry
Gokulapriya Baskar, Gokul Jayavel, Suji Saravanan, Selvapandiyan Marimuthu
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Abstract

Biomass-derived activated carbon are emerging as a sustainable electrode for high-performance supercapacitors. Mango seed-derived activated carbon was synthesized using chemical activation with H3PO4 as an activating agent. Brunauer Emmett Teller (BET) analysis of MSAC@800 revealed a high specific surface area of 818 m2/g, providing abundant active sites for ion adsorption. XRD and Raman analyses confirmed that the activated carbon is partially graphitized structure, which improves the electrical conductivity. FE—SEM showed a well-developed porous structure that facilitates efficient ion transport. Fourier Transform Infrared (FTIR) analysis confirmed the presence of a functional group that enhances the electrochemical performance. MSAC@800 electrode exhibited a specific capacitance of 336.94 ± 0.16 F/g and an energy density of 46.76 ± 0.09 Wh/kg at a current density of 2 A/g. The capacitive-controlled contribution reached 85 %, this enhancing the overall capacitance and energy storage. This study demonstrates that mango seed-derived activated carbon is a cost-effective and high-performance electrode material for supercapacitor applications.

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温度调制纳米结构对芒果籽制备的高能超级电容器电极电化学性能的影响
生物质来源的活性炭正在成为高性能超级电容器的可持续电极。以H3PO4为活化剂,采用化学活化法合成芒果籽活性炭。Brunauer Emmett Teller (BET)对MSAC@800的分析表明,其比表面积高达818 m2/g,为离子吸附提供了丰富的活性位点。XRD和Raman分析证实活性炭为部分石墨化结构,提高了导电性能。FE-SEM显示了发育良好的多孔结构,有利于离子的高效传输。傅里叶变换红外(FTIR)分析证实了增强电化学性能的官能团的存在。MSAC@800电极在电流密度为2 a /g时的比电容为336.94±0.16 F/g,能量密度为46.76±0.09 Wh/kg。电容控制的贡献达到85%,这提高了整体电容和能量存储。本研究表明,芒果籽活性炭是一种经济高效的超级电容器电极材料。
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来源期刊
CiteScore
2.50
自引率
6.70%
发文量
121
审稿时长
1.9 months
期刊介绍: The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing
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