Oil Structuring Using Stearin Fractions Derived From Slaughterhouse By-Products: Effect of Gelator and Oil Type on Physicochemical Characteristics of Structured Oil

IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED
Maryam Abdollahi, Sayed Amir Hossein Goli, Nafiseh Soltanizadeh, Sonia Calligaris
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Abstract

This study evaluated the potential of utilizing the stearin fraction of sheep tail and ostrich fats, as by-products of slaughterhouses, to structure various oils (canola, sesame, sunflower, and flaxseed oils). A stable gel was formed at 25% sheep tail stearins (STS) and 30% ostrich stearins (OSS). STS-based structured oils showed needle-like crystals, longer gelling time (19.14–24.75 min), and firmer structure (1.65–2.09 N) alongside higher elastic modulus (G′) and lower oil loss (< 11%) compared to OSS-based, which contained bigger rosette-like crystals. Moreover, oils with higher unsaturation levels and iodine values resulted in lower viscosity, accelerated crystallization rate, improved firmness, and enhanced oil retention. STS-based structured oil showed β'-polymorph, leading to a stronger network and higher melting enthalpy, which completely melted near body temperature, in contrast to the β-polymorph structure of the OSS-based counterpart. Hence, the type of structurant and oil significantly affected the oil structuring process. The oleogel containing flaxseed oil and STS can replace hydrogenated fats (such as shortenings) in food formulations, offering similar textural and melting properties while improving their nutritional profile.

Abstract Image

利用从屠宰场副产品中提取的硬脂质馏分构建油结构:凝胶和油类型对结构化油理化特性的影响
本研究评估了利用羊尾和鸵鸟脂肪的硬脂脂部分作为屠宰场的副产品来制造各种油(菜籽油、芝麻油、葵花籽油和亚麻籽油)的潜力。在25%的羊尾硬脂(STS)和30%的鸵鸟硬脂(OSS)中形成稳定的凝胶。与含有更大的玫瑰花状晶体的oss相比,sts基结构油具有针状晶体、更长的胶凝时间(19.14 ~ 24.75 min)、更坚固的结构(1.65 ~ 2.09 N)、更高的弹性模量(G′)和更低的油损(< 11%)。此外,具有较高不饱和水平和碘值的油可以降低粘度,加快结晶速度,改善硬度,增强油潴留。sts结构油呈现β′-多晶型,网状结构更强,熔化焓更高,在接近体温时完全熔化,而oss结构油呈现β′-多晶型结构。因此,构造剂和油类的类型对成油过程有显著影响。含有亚麻籽油和STS的油凝胶可以取代食品配方中的氢化脂肪(如起酥油),提供类似的质地和熔化特性,同时改善其营养成分。
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来源期刊
CiteScore
4.10
自引率
5.00%
发文量
95
审稿时长
2.4 months
期刊介绍: The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate. JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of year­to­year, environmental, and/ or cultivar variations through use of appropriate statistical analyses.
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