“In situ preparation of 3D flower like BiOBr/Bi24O31Br10 composite by annealing hydrothermal method for the ciprofloxacin degradation under simulated sunlight irradiation”
IF 4.6 3区 工程技术Q2 ENGINEERING, ELECTRICAL & ELECTRONIC
L. Mllaoiy , S. Bikerchalen , B. Akhsassi , B. Bakiz , S. Villain , A. Taoufyq , F. Guinneton , H. Hajjoul , J.-R. Gavarri , A. Benlhachemi
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引用次数: 0
Abstract
In this work, a hierarchical photocatalyst, BiOBr/Bi24O31Br10, was synthesized via a simple two-step hydrothermal and annealing process. The BiOBr/Bi24O31Br10 microstructure exhibited significantly enhanced photocatalytic performance compared to pure BiOBr and Bi24O31Br10. Under simulated solar irradiation, it achieved 94 % degradation of ciprofloxacin (CIP) in 60 min, with a reaction rate 5.5 times higher than that of pure Bi24O31Br10. Rhodamine B (RhB) was also thoroughly degraded in 20 min. This improvement was attributed to several synergistic effects: the increased BET surface area provided more active sites; the enhanced adsorption capacity toward CIP facilitated its efficient degradation; and the broadened sunlight absorption range promoted the generation of charge carriers with an extended lifetime of 5.70 ns, surpassing that of the individual components. Additionally, the influence of operating parameters such as initial pH, photocatalyst dosage, initial pollutant concentration, and light intensity was systematically investigated.
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