{"title":"High performance room-temperature NH3 sensor based on WO3/ZnO heterostructure","authors":"Yongqiang Liu , Jin Li","doi":"10.1016/j.mssp.2025.109992","DOIUrl":null,"url":null,"abstract":"<div><div>Reliable selectivity and low power consumption are two inevitable requirements for the new generation of gas sensors. In this paper, NH<sub>3</sub> sensors based on WO<sub>3</sub>/ZnO with high sensing performance at room temperature were prepared. Compared with the conventional WO<sub>3</sub>-based gas-sensitive sensor, the WO<sub>3</sub>/ZnO-2 gas-sensitive sensor exhibits high response (91.62, 50 ppm), high selectivity, and long-term stability at room temperature. Moreover, it also achieves fast response/recovery times (3.5 s/1.6 s) and low theoretical limit of detection (0.127 ppm), which makes it possible to detect the presence of low concentrations of NH<sub>3</sub> quickly. The excellent gas-sensitive performance of the sensor can be ascribed to the synergistic interaction between WO<sub>3</sub> and ZnO, as well as the increase in oxygen vacancy and adsorbed oxygen content. This study provides guidance for developing cost-effective and high-performance room temperature NH<sub>3</sub> sensors.</div></div>","PeriodicalId":18240,"journal":{"name":"Materials Science in Semiconductor Processing","volume":"200 ","pages":"Article 109992"},"PeriodicalIF":4.6000,"publicationDate":"2025-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science in Semiconductor Processing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1369800125007292","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Reliable selectivity and low power consumption are two inevitable requirements for the new generation of gas sensors. In this paper, NH3 sensors based on WO3/ZnO with high sensing performance at room temperature were prepared. Compared with the conventional WO3-based gas-sensitive sensor, the WO3/ZnO-2 gas-sensitive sensor exhibits high response (91.62, 50 ppm), high selectivity, and long-term stability at room temperature. Moreover, it also achieves fast response/recovery times (3.5 s/1.6 s) and low theoretical limit of detection (0.127 ppm), which makes it possible to detect the presence of low concentrations of NH3 quickly. The excellent gas-sensitive performance of the sensor can be ascribed to the synergistic interaction between WO3 and ZnO, as well as the increase in oxygen vacancy and adsorbed oxygen content. This study provides guidance for developing cost-effective and high-performance room temperature NH3 sensors.
期刊介绍:
Materials Science in Semiconductor Processing provides a unique forum for the discussion of novel processing, applications and theoretical studies of functional materials and devices for (opto)electronics, sensors, detectors, biotechnology and green energy.
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Coverage will include: advanced lithography for submicron devices; etching and related topics; ion implantation; damage evolution and related issues; plasma and thermal CVD; rapid thermal processing; advanced metallization and interconnect schemes; thin dielectric layers, oxidation; sol-gel processing; chemical bath and (electro)chemical deposition; compound semiconductor processing; new non-oxide materials and their applications; (macro)molecular and hybrid materials; molecular dynamics, ab-initio methods, Monte Carlo, etc.; new materials and processes for discrete and integrated circuits; magnetic materials and spintronics; heterostructures and quantum devices; engineering of the electrical and optical properties of semiconductors; crystal growth mechanisms; reliability, defect density, intrinsic impurities and defects.