Natural waxes from plant and animal origin as dielectrics for low-voltage organic field effect transistors

IF 5.1 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Cristian Vlad Irimia, Cigdem Yumusak, Yasin Kanbur, Corina Schimanofsky, Boyuan Ban, Martin Ciganek, Petr Sedlacek, Jozef Krajcovic, Rosarita D’Orsi, Alessandra Operamolla, Oliver Brüggemann, Yolanda Salinas, Andreas Petritz, Barbara Stadlober, Rahul Mourya, Christian Teichert, Heinz Langhals, Niyazi Serdar Sariciftci and Mihai Irimia-Vladu
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Abstract

We demonstrate in this work the practical use of naturally extracted waxes of plant and animal origin, i.e., beeswax, carnauba wax, rice bran wax, lanolin wax, and two shellac waxes as dielectrics in organic field effect transistors (OFETs). We present a thorough characterization of their material properties, processability and film forming characteristic, surface characterization, dielectric investigation and the fabrication of field effect transistors with two classic organic semiconductors, i.e., pentacene and fullerene C60. We show that operating voltages as low as 1 V are possible for all the OFETs using blade coating as fabrication method of waxes solubilized in their appropriate solvent, chloroform or n-octane. Although in general difficult to process in thin films, we demonstrate in this work the practical applicability of these natural waxes for electronics fabrication.

Abstract Image

来自植物和动物的天然蜡作为低压有机场效应晶体管的介电材料。
在这项工作中,我们展示了天然提取的植物和动物蜡,即蜂蜡、巴西棕榈蜡、米糠蜡、羊毛脂蜡和两种紫胶蜡作为有机场效应晶体管(ofet)的介电材料的实际应用。本文介绍了其材料性能、可加工性和成膜特性、表面表征、介电特性研究以及两种经典有机半导体(即并五苯和富勒烯C60)的场效应晶体管的制备。我们表明,使用叶片涂层作为蜡溶解在适当的溶剂氯仿或正辛烷中的制造方法,所有的ofet都可以实现低至1 V的工作电压。虽然通常难以在薄膜中加工,但我们在这项工作中证明了这些天然蜡在电子制造中的实际适用性。
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来源期刊
Journal of Materials Chemistry C
Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
10.80
自引率
6.20%
发文量
1468
期刊介绍: The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors
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