Near-collector electroprinting of cellulose acetate structures with large specific surface per volume

IF 2.8 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC
Farnaz Rezaei , Daniel O. Carlsson , Jimmy Hedin Dahlstrom , Jonas Lindh , Stefan Johansson
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Abstract

This study focuses on the fabrication and analysis of 3D-printed high-detail resolution cellulose acetate (CA) structures, particularly examining their specific surface area per volume Sv. While electrospinning is a widely used technique for creating nanofiber membranes with high Sv, which is advantageous for applications like chromatography, the performance could be further improved by precisely controlling fiber placement. To further develop membranes, this research explores the use of electroprinting with small distances between nozzle and collector, here named near-collector electroprinting, to create 3D structures. By optimizing printing parameters, in particular the reduction of the nozzle-to-collector distance, 3D structures with precise fiber placement within a few micrometers were fabricated. The specific surface area per volume was calculated for both 3D-printed and electrospun filters. Results showed that 3D-printed structures with a 5 μm pitch achieved a Sv similar to electrospun filters.
Incorporating polyethyleneimine (PEI) in the CA ink enabled the 3D-printed structures to gain ion binding capacity which was further investigated. This ion-exchange ability which integrated into the printing step, eliminating the need for a separate post-modification process in bio-separation applications. By switching the substrate voltage from positive to negative, relative to the grounded nozzle, the printed fiber diameter decreased substantially for the CA ink with PEI. The Sv for near-collector electroprinted fibers of this material could therefore potentially be higher than that of electrospun membranes, provided that an order of magnitude higher printing speed, than presently possible can be used. These findings suggest that near-collector electroprinted CA structures offer potential improvements in membrane design and performance, making them a promising alternative to traditional electrospun membranes for bio-separation applications.

Abstract Image

具有大体积比表面积的醋酸纤维素结构的近捕集器电印刷
本研究侧重于3d打印高细节分辨率醋酸纤维素(CA)结构的制造和分析,特别是检查其每体积比表面积Sv。虽然静电纺丝是一种广泛使用的技术,用于制造高Sv的纳米纤维膜,这有利于色谱等应用,但通过精确控制纤维的放置可以进一步提高性能。为了进一步开发膜,本研究探索了喷嘴和集热器之间距离较小的电打印技术的使用,这里称为近集热器电打印,以创建3D结构。通过优化打印参数,特别是减少喷嘴到收集器的距离,可以制造出在几微米内精确放置纤维的3D结构。计算了3d打印和静电纺过滤器的每体积比表面积。结果表明,间距为5 μm的3d打印结构获得了与静电纺过滤器相似的Sv。在CA墨水中加入聚乙烯亚胺(PEI)使3d打印结构获得离子结合能力,这一点得到了进一步的研究。这种离子交换能力集成到打印步骤中,消除了生物分离应用中单独的后修饰过程的需要。相对于接地喷嘴,通过将衬底电压从正开关到负开关,具有PEI的CA油墨的印刷纤维直径大大减小。因此,这种材料的近集电极电印刷纤维的Sv可能比电纺膜的Sv高,前提是可以使用比目前可能的印刷速度高一个数量级。这些发现表明,近集热器电印刷CA结构在膜设计和性能方面有潜在的改进,使其成为传统电纺膜在生物分离应用中的有希望的替代品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Micro and Nano Engineering
Micro and Nano Engineering Engineering-Electrical and Electronic Engineering
CiteScore
3.30
自引率
0.00%
发文量
67
审稿时长
80 days
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