{"title":"Switchable Behavior and Applications of Low-Dimensional Halide Perovskites under External Environmental Stimuli","authors":"Ruirui Wu, Shunfa Gong, Yijun Wu, Zhiyuan Ren, Huan Liu, Daniela Marongiu, Michele Saba, Rui Chen","doi":"10.1002/crat.202400251","DOIUrl":null,"url":null,"abstract":"<p>The flexibility and adaptability of low-dimensional halide perovskites make them ideal candidates for a wide range of cutting-edge technologies. In addition to their primary applications in photovoltaics, they have recently attracted attention for their potential use in switchable technologies such as smart windows, encrypted messages, and sensors. The interest stems from their switchable properties, which enable them to change their physical properties, in particular photoluminescence and crystal color, in response to external stimuli such as heat, light, pressure, and humidity. This review examines their switchable properties and explores their practical applications in a number of emerging chromic technologies. This paper also provides an in-depth analysis of the reversibility, switchable optical and electrical properties of low-dimensional halide perovskites, and the switching mechanisms involved in the transformations they undergo. In addition, the paper is classified according to different switching mechanisms. To assist the research community in developing new designs for new switchable low-dimensional perovskites, some basic criteria for effective switching materials are outlined here. Finally, the current challenges facing these emerging materials are discussed, and an outlook on future developments and potential breakthroughs in this promising area of research is provided.</p>","PeriodicalId":48935,"journal":{"name":"Crystal Research and Technology","volume":"60 5","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Research and Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/crat.202400251","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 0
Abstract
The flexibility and adaptability of low-dimensional halide perovskites make them ideal candidates for a wide range of cutting-edge technologies. In addition to their primary applications in photovoltaics, they have recently attracted attention for their potential use in switchable technologies such as smart windows, encrypted messages, and sensors. The interest stems from their switchable properties, which enable them to change their physical properties, in particular photoluminescence and crystal color, in response to external stimuli such as heat, light, pressure, and humidity. This review examines their switchable properties and explores their practical applications in a number of emerging chromic technologies. This paper also provides an in-depth analysis of the reversibility, switchable optical and electrical properties of low-dimensional halide perovskites, and the switching mechanisms involved in the transformations they undergo. In addition, the paper is classified according to different switching mechanisms. To assist the research community in developing new designs for new switchable low-dimensional perovskites, some basic criteria for effective switching materials are outlined here. Finally, the current challenges facing these emerging materials are discussed, and an outlook on future developments and potential breakthroughs in this promising area of research is provided.
期刊介绍:
The journal Crystal Research and Technology is a pure online Journal (since 2012).
Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of
-crystal growth techniques and phenomena (including bulk growth, thin films)
-modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals)
-industrial crystallisation
-application of crystals in materials science, electronics, data storage, and optics
-experimental, simulation and theoretical studies of the structural properties of crystals
-crystallographic computing