Switchable Behavior and Applications of Low-Dimensional Halide Perovskites under External Environmental Stimuli

IF 1.5 4区 材料科学 Q3 Chemistry
Ruirui Wu, Shunfa Gong, Yijun Wu, Zhiyuan Ren, Huan Liu, Daniela Marongiu, Michele Saba, Rui Chen
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Abstract

The flexibility and adaptability of low-dimensional halide perovskites make them ideal candidates for a wide range of cutting-edge technologies. In addition to their primary applications in photovoltaics, they have recently attracted attention for their potential use in switchable technologies such as smart windows, encrypted messages, and sensors. The interest stems from their switchable properties, which enable them to change their physical properties, in particular photoluminescence and crystal color, in response to external stimuli such as heat, light, pressure, and humidity. This review examines their switchable properties and explores their practical applications in a number of emerging chromic technologies. This paper also provides an in-depth analysis of the reversibility, switchable optical and electrical properties of low-dimensional halide perovskites, and the switching mechanisms involved in the transformations they undergo. In addition, the paper is classified according to different switching mechanisms. To assist the research community in developing new designs for new switchable low-dimensional perovskites, some basic criteria for effective switching materials are outlined here. Finally, the current challenges facing these emerging materials are discussed, and an outlook on future developments and potential breakthroughs in this promising area of research is provided.

Abstract Image

低维卤化物钙钛矿在外界环境刺激下的转换行为及其应用
低维卤化物钙钛矿的灵活性和适应性使其成为各种尖端技术的理想候选者。除了它们在光伏方面的主要应用外,它们最近还因其在智能窗口、加密信息和传感器等可切换技术中的潜在用途而引起了人们的注意。这种兴趣源于它们的可切换特性,这使它们能够改变其物理特性,特别是光致发光和晶体颜色,以响应外部刺激,如热、光、压力和湿度。本文综述了它们的可切换特性,并探讨了它们在一些新兴的铬技术中的实际应用。本文还深入分析了低维卤化物钙钛矿的可逆性、可切换的光学和电学性质,以及它们所经历的转换所涉及的开关机制。此外,本文还根据不同的切换机制进行了分类。为了帮助研究团体开发新的可切换低维钙钛矿的新设计,本文概述了有效开关材料的一些基本标准。最后,讨论了这些新兴材料目前面临的挑战,并展望了这一前景广阔的研究领域的未来发展和潜在突破。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
2.50
自引率
6.70%
发文量
121
审稿时长
1.9 months
期刊介绍: The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing
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