{"title":"Laser-driven composite ceramic enabling superhigh‐luminance white light","authors":"Rundong Tian, Tianliang Zhou, Rong-Jun Xie","doi":"10.1016/j.jmat.2025.101059","DOIUrl":null,"url":null,"abstract":"Laser-remote activated phosphor (LARP) converted solid state lighting is now developing towards high power density and super-brightness, and phosphor ceramic converters with high efficiency, high thermal conductivity, acceptable transmittance and suitable spectra are thus required. Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>:Ce (YAG:Ce)-based ceramics are promising color converters to produce white light with a color temperature of 6000 K for vehicle headlamps, but the brightness and luminous efficiency are not well optimized. In this work, two series of Al<sub>2</sub>O<sub>3</sub>-YAG:Ce and Al<sub>2</sub>O<sub>3</sub>-(Gd,Y)AG:Ce transparent ceramics were fabricated by vacuum sintering, and their microstructure, thermal and optical properties were controlled by changing the Ce<sup>3+</sup> or Al<sub>2</sub>O<sub>3</sub> content as well the thickness of the ceramics. Both Al<sub>2</sub>O<sub>3</sub>-Y<sub>2.925</sub>Al<sub>5</sub>O<sub>12</sub>:Ce<sub>0.0175</sub> (AY0.0175) and Al<sub>2</sub>O<sub>3</sub>-(Gd<sub>0.1</sub>Y<sub>2.89</sub>)Al<sub>5</sub>O<sub>12</sub>:Ce<sub>0.01</sub> (AGY) ceramics containing 70% (in mass) Al<sub>2</sub>O<sub>3</sub> show a luminance saturation threshold of 30.3 W/mm<sup>2</sup> and 38.4 W/mm<sup>2</sup>, enabling to produce white light with a color temperature of 6000 K, luminous flux of 1928 lm and 3101 lm, luminous efficiency of 135.0 lm/W and 161.1 lm/W when pumped by blue laser diodes, respectively. This work provides a solution to finely control the composition, microstructure, and optical properties of transparent ceramics for super-high brightness laser-driven solid-state lighting.","PeriodicalId":16173,"journal":{"name":"Journal of Materiomics","volume":"23 1","pages":""},"PeriodicalIF":8.4000,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materiomics","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.jmat.2025.101059","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Laser-remote activated phosphor (LARP) converted solid state lighting is now developing towards high power density and super-brightness, and phosphor ceramic converters with high efficiency, high thermal conductivity, acceptable transmittance and suitable spectra are thus required. Y3Al5O12:Ce (YAG:Ce)-based ceramics are promising color converters to produce white light with a color temperature of 6000 K for vehicle headlamps, but the brightness and luminous efficiency are not well optimized. In this work, two series of Al2O3-YAG:Ce and Al2O3-(Gd,Y)AG:Ce transparent ceramics were fabricated by vacuum sintering, and their microstructure, thermal and optical properties were controlled by changing the Ce3+ or Al2O3 content as well the thickness of the ceramics. Both Al2O3-Y2.925Al5O12:Ce0.0175 (AY0.0175) and Al2O3-(Gd0.1Y2.89)Al5O12:Ce0.01 (AGY) ceramics containing 70% (in mass) Al2O3 show a luminance saturation threshold of 30.3 W/mm2 and 38.4 W/mm2, enabling to produce white light with a color temperature of 6000 K, luminous flux of 1928 lm and 3101 lm, luminous efficiency of 135.0 lm/W and 161.1 lm/W when pumped by blue laser diodes, respectively. This work provides a solution to finely control the composition, microstructure, and optical properties of transparent ceramics for super-high brightness laser-driven solid-state lighting.
期刊介绍:
The Journal of Materiomics is a peer-reviewed open-access journal that aims to serve as a forum for the continuous dissemination of research within the field of materials science. It particularly emphasizes systematic studies on the relationships between composition, processing, structure, property, and performance of advanced materials. The journal is supported by the Chinese Ceramic Society and is indexed in SCIE and Scopus. It is commonly referred to as J Materiomics.