{"title":"Synthesis and photosensitized hydrogen production of WO3-WS2 composite","authors":"Miaomiao Xue, Mingcai Yin, Dehang Ma, Jiaming Zhang, Luyao Ling, Yaoting Fan","doi":"10.1016/j.mssp.2025.109526","DOIUrl":null,"url":null,"abstract":"<div><div>WO<sub>3</sub> is one of the most potential photocatalysts. However, to realize its photocatalytic hydrogen production, modification such as combining with WS<sub>2</sub> is necessary due to its poor reduction capacity. To find out the optimal ratio between WO<sub>3</sub> and WS<sub>2</sub>, in this paper, a facile two-step calcination method was used for the preparation of a series of WO<sub>3</sub>-WS<sub>2</sub> composites, and their photocatalytic hydrogen performances were investigated under Erythrosine B sodium salt (EB) sensitization. The results showed that when the mass ratio of WS<sub>2</sub> to WO<sub>3</sub> is 5:5 or higher, efficient hydrogen evolution comes true. In addition, the calcination condition for the preparation of precursor WO<sub>3</sub> and the method for the preparation of WO<sub>3</sub>-WS<sub>2</sub> composite were optimized. The as-prepared WO<sub>3</sub>-WS<sub>2</sub> exhibits relatively good stability and relatively stable hydrogen generation was achieved when CdS was introduced.</div></div>","PeriodicalId":18240,"journal":{"name":"Materials Science in Semiconductor Processing","volume":"194 ","pages":"Article 109526"},"PeriodicalIF":4.2000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science in Semiconductor Processing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S136980012500263X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
WO3 is one of the most potential photocatalysts. However, to realize its photocatalytic hydrogen production, modification such as combining with WS2 is necessary due to its poor reduction capacity. To find out the optimal ratio between WO3 and WS2, in this paper, a facile two-step calcination method was used for the preparation of a series of WO3-WS2 composites, and their photocatalytic hydrogen performances were investigated under Erythrosine B sodium salt (EB) sensitization. The results showed that when the mass ratio of WS2 to WO3 is 5:5 or higher, efficient hydrogen evolution comes true. In addition, the calcination condition for the preparation of precursor WO3 and the method for the preparation of WO3-WS2 composite were optimized. The as-prepared WO3-WS2 exhibits relatively good stability and relatively stable hydrogen generation was achieved when CdS was introduced.
期刊介绍:
Materials Science in Semiconductor Processing provides a unique forum for the discussion of novel processing, applications and theoretical studies of functional materials and devices for (opto)electronics, sensors, detectors, biotechnology and green energy.
Each issue will aim to provide a snapshot of current insights, new achievements, breakthroughs and future trends in such diverse fields as microelectronics, energy conversion and storage, communications, biotechnology, (photo)catalysis, nano- and thin-film technology, hybrid and composite materials, chemical processing, vapor-phase deposition, device fabrication, and modelling, which are the backbone of advanced semiconductor processing and applications.
Coverage will include: advanced lithography for submicron devices; etching and related topics; ion implantation; damage evolution and related issues; plasma and thermal CVD; rapid thermal processing; advanced metallization and interconnect schemes; thin dielectric layers, oxidation; sol-gel processing; chemical bath and (electro)chemical deposition; compound semiconductor processing; new non-oxide materials and their applications; (macro)molecular and hybrid materials; molecular dynamics, ab-initio methods, Monte Carlo, etc.; new materials and processes for discrete and integrated circuits; magnetic materials and spintronics; heterostructures and quantum devices; engineering of the electrical and optical properties of semiconductors; crystal growth mechanisms; reliability, defect density, intrinsic impurities and defects.