Cantilever-Enhanced Photoacoustic Spectroscopy: Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF6 Decomposition Components

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Hongtu Cheng, Jie Feng, Yang Shen, Zhi Fang
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引用次数: 0

Abstract

Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H2S and CO2, both of which have been identified as typical fault gases in SF6 gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H2S and CO2 by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H2S and CO2 are 2.55 and 84.69 ppm, respectively.

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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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