Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization†

IF 5.7 2区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Journal of Materials Chemistry C Pub Date : 2025-03-05 DOI:10.1039/D5TC00556F

Yunfeng Fang, Yuchen Zhang, Leopoldo Suescun, Mingyue Chen, Zhen Song and Quanlin Liu

引用次数: 0

Abstract

Sb-based metal halides have been a research focus because of their excellent optical properties. Pyramid-like [SbCl₅] polyhedra are the most distinct crystallographic feature. We analyzed 56 luminescent Sb-based hybrids from a list of 120 Sb chlorides by finding the corresponding best fitted ideal polyhedron. The results show a significant correlation between the distortion and photoluminescent quantum yield.

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来源期刊

Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED

CiteScore

10.80

自引率

6.20%

发文量

1468

期刊介绍： The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors