Micrometric Co3O4/ZIF-67 with high toluene detection capability

Abstract

Environmental monitoring has increasingly focused on detecting volatile organic compounds (VOCs), especially toluene, as these substances pose significant environmental and human health risks. Our research demonstrates the fabrication of microscale Co₃O₄, a p-type semiconductor material, synthesized through a two-step process combining microwave-assisted hydrothermal synthesis and subsequent calcination. Given the inherent low sensitivity and selectivity of p-type metal oxide semiconductor (MOS) sensors, we explored strategies to enhance the selectivity and sensitivity of p-type MOS under diverse sensing conditions, including varying temperatures and humid environments. The VOC detection performance of Co₃O₄ was improved by adding a metal-organic framework, ZIF-67. The Co₃O₄/ZIF-67 composite was prepared using the reflux method. The sensor demonstrated enhanced detection capabilities compared to pure Co₃O₄, as evidenced by the Co₃O₄/ZIF-67 composite exhibiting the highest response (61.22) to 100 ppm of toluene at 250 °C, with a high selectivity index (5.43). In contrast, the Co₃O₄ sensor responded 20.05 to toluene, with a relatively low selectivity index (2.86) at 250 °C. Therefore, the incorporation of ZIF-67 resulted in an enhancement of the sensor's response and selectivity. Furthermore, the sensor demonstrated satisfactory performance at various controlled relative humidities. The micro-sized Co₃O₄/ZIF-67 demonstrates significant potential as an effective material for low-temperature toluene detection, a crucial capability for monitoring environmental conditions and protecting human health.