Dual-Component Gas Sensor Based on Light-Induced Thermoelastic Spectroscopy and Deep Learning

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Jinfeng Hou, Xiaonan Liu, Haiyue Sun, Ying He, Shunda Qiao, Weijiang Zhao, Sheng Zhou and Yufei Ma*, 
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引用次数: 0

Abstract

In this paper, an acetylene–carbon dioxide dual-component gas sensor based on light-induced thermoelastic spectroscopy and deep learning is reported for the first time. Two lasers with wavelengths of 1530 and 1577 nm were coupled by a wavelength division multiplexer to excite the two gas molecules. The sensor combined four algorithms, namely, sparrow search algorithm (SSA), convolutional neural network (CNN), bidirectional gated recurrent unit neural network (BiGRU), and attention mechanism (Attention), to achieve two-component gas concentration inversion in three cases, in which the overlap of the two gas spectral lines is different. The advantage of the combination of the SSA-CNN-BiGRU-Attention model is that the weight can be assigned according to the characteristics of the second harmonic (2f) signal itself, and the optimal parameters can be automatically found. The SSA-CNN-BiGRU-Attention model effectively improved the accuracy of concentration inversion and significantly reduced the mean relative error (MRE). The experimental results show that the R-square values of the test set are all greater than 0.99, and the MRE is less than 1.2%, showing a high concentration inversion accuracy. This work provides instructions for the absorption line overlap in dual-component gas detection and is expected to be applied to the study of concentration inversion of more gas components in the future.

Abstract Image

基于光致热弹性光谱和深度学习的双组分气体传感器
本文首次报道了一种基于光致热弹性光谱和深度学习的乙炔-二氧化碳双组分气体传感器。两个波长分别为1530 nm和1577 nm的激光通过波分多路复用器耦合来激发两个气体分子。该传感器结合了麻雀搜索算法(SSA)、卷积神经网络(CNN)、双向门控循环单元神经网络(BiGRU)和注意机制(attention)四种算法,实现了两种气体谱线重叠不同的三种情况下的双组分气体浓度反演。SSA-CNN-BiGRU-Attention模型组合的优点是可以根据二次谐波(2f)信号本身的特征来分配权重,并自动找到最优参数。SSA-CNN-BiGRU-Attention模型有效提高了浓度反演的精度,显著降低了平均相对误差(MRE)。实验结果表明,测试集的r方值均大于0.99,MRE小于1.2%,具有较高的浓度反演精度。本工作为双组分气体检测中的吸收线重叠提供了指导,有望应用于未来更多气体组分浓度反演的研究。
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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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