Hydro-locking in hydrogel for extreme temperature tolerance.

IF 45.8 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES
Science Pub Date : 2025-02-28 Epub Date: 2025-02-27 DOI:10.1126/science.adq2711
Xiaochen Zhang, Dong Li, Xuxu Yang, Lei Wang, Guo Li, Tuck-Whye Wong, Tiefeng Li, Wei Yang, Zisheng Luo
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引用次数: 0

Abstract

Hydrogels consist of cross-linked polymers that are highly swollen with water. Water evaporation or freezing during temperature changes may lead to stiff and brittle hydrogels. We introduce a strategy called "hydro-locking," which involves immobilizing the water molecules within the polymer network of the hydrogel. This is accomplished by establishing robust connections between water molecules and the polymer by using sulfuric acid. A sacrificial network is introduced to shield the prime polymer network from collapsing. Under the hydro-locking mode, an alginate-polyacrylamide double-network hydrogel remains soft and stretchable within a temperature range that spans from -115° to 143°C. The strategy works with a range of hydrogels and solutions and may enable the preservation and observation of materials or even living organisms at extreme temperatures.

水凝胶中的水锁,具有极端的耐温性。
水凝胶由交联的聚合物组成,这些聚合物在水中高度膨胀。在温度变化过程中,水的蒸发或冻结可能导致水凝胶变硬变脆。我们介绍了一种叫做“水锁”的策略,它包括将水分子固定在水凝胶的聚合物网络中。这是通过使用硫酸在水分子和聚合物之间建立牢固的连接来实现的。引入了一种牺牲网络来保护原生聚合物网络不崩溃。在水锁模式下,海藻酸盐-聚丙烯酰胺双网水凝胶在-115°C至143°C的温度范围内保持柔软和可拉伸。该策略适用于一系列水凝胶和溶液,可以在极端温度下保存和观察材料甚至生物体。
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来源期刊
Science
Science 综合性期刊-综合性期刊
CiteScore
61.10
自引率
0.90%
发文量
0
审稿时长
2.1 months
期刊介绍: Science is a leading outlet for scientific news, commentary, and cutting-edge research. Through its print and online incarnations, Science reaches an estimated worldwide readership of more than one million. Science’s authorship is global too, and its articles consistently rank among the world's most cited research. Science serves as a forum for discussion of important issues related to the advancement of science by publishing material on which a consensus has been reached as well as including the presentation of minority or conflicting points of view. Accordingly, all articles published in Science—including editorials, news and comment, and book reviews—are signed and reflect the individual views of the authors and not official points of view adopted by AAAS or the institutions with which the authors are affiliated. Science seeks to publish those papers that are most influential in their fields or across fields and that will significantly advance scientific understanding. Selected papers should present novel and broadly important data, syntheses, or concepts. They should merit recognition by the wider scientific community and general public provided by publication in Science, beyond that provided by specialty journals. Science welcomes submissions from all fields of science and from any source. The editors are committed to the prompt evaluation and publication of submitted papers while upholding high standards that support reproducibility of published research. Science is published weekly; selected papers are published online ahead of print.
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