Advances in spinel-type electrocatalysts: Leveraging ligand field theory to elucidate structure-property relationships

IF 8.4 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Journal of Materiomics Pub Date : 2025-02-21 DOI:10.1016/j.jmat.2025.101031

Xin Li , Zongkui Kou , Jiayan Dai , Hao Sun , John Wang , Shiyou Zheng

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Abstract

Spinels have been widely concerned as a promising class of electrocatalysts due to their appealing catalytic properties and the tunability of their compositions and structures. Ligand field theory (LFT), which describes the origins and the consequences of metal-ligand interactions, offers crucial insights for the design of spinel-type electrocatalysts. In this review, we timely summarize the research progress of spinel electrocatalysts that leverage LFT for structure-property insights, providing a pioneering perspective in this field. This review explores how LFT plays a pivotal role in optimizing the electrocatalytic properties of spinels. It covers important aspects such as identifying the origin of the catalytic properties, tuning the number of active sites, manipulating the e_g-filling and the spin state of metal cations, and modulating the 2p band of ligands. We anticipate that this review will provide valuable theoretical guidance and inspire creative spinel designs that excel in electrocatalytic applications.

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来源期刊

Journal of Materiomics Materials Science-Metals and Alloys

CiteScore

14.30

自引率

6.40%

发文量

331

审稿时长

37 days

期刊介绍： The Journal of Materiomics is a peer-reviewed open-access journal that aims to serve as a forum for the continuous dissemination of research within the field of materials science. It particularly emphasizes systematic studies on the relationships between composition, processing, structure, property, and performance of advanced materials. The journal is supported by the Chinese Ceramic Society and is indexed in SCIE and Scopus. It is commonly referred to as J Materiomics.