Dongjie Yang , Yaoyao Liu , Xiang Zhang , Shusheng Chen , Xiaowei Wang , Yu Liao , Xiaokai An , Yanfei Zhao , Lingjie Chen , Suihan Cui , Liangliang Liu , Ricky K Y Fu , Paul K Chu , Zhongzhen Wu
{"title":"Dense Al2O3 films prepared by high power impulse magnetron sputtering at pulsed kV bias","authors":"Dongjie Yang , Yaoyao Liu , Xiang Zhang , Shusheng Chen , Xiaowei Wang , Yu Liao , Xiaokai An , Yanfei Zhao , Lingjie Chen , Suihan Cui , Liangliang Liu , Ricky K Y Fu , Paul K Chu , Zhongzhen Wu","doi":"10.1016/j.tsf.2025.140611","DOIUrl":null,"url":null,"abstract":"<div><div>Al<sub>2</sub>O<sub>3</sub> films are often used in electronic and other devices for surface protection due to their excellent insulating and mechanical properties, but these properties depend on the film density. Conventional magnetron sputtering used industrially to deposit Al<sub>2</sub>O<sub>3</sub> films faces challenges in density regulation, and many Al<sub>2</sub>O<sub>3</sub> coatings have poor densities. Herein, negative kV biases are applied to the substrate in high-power impulse magnetron sputtering (HiPIMS) to produce the desirable high-energy ions to densify the Al<sub>2</sub>O<sub>3</sub> films. Our results indicate that the high pulsed bias also mitigates arcing during the deposition of insulating alumina films. By increasing the pulsed voltage, the film density increases, resulting in higher optical transparency, better insulating and mechanical properties, as well as superior corrosion resistance.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"811 ","pages":"Article 140611"},"PeriodicalIF":2.0000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thin Solid Films","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040609025000124","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
Abstract
Al2O3 films are often used in electronic and other devices for surface protection due to their excellent insulating and mechanical properties, but these properties depend on the film density. Conventional magnetron sputtering used industrially to deposit Al2O3 films faces challenges in density regulation, and many Al2O3 coatings have poor densities. Herein, negative kV biases are applied to the substrate in high-power impulse magnetron sputtering (HiPIMS) to produce the desirable high-energy ions to densify the Al2O3 films. Our results indicate that the high pulsed bias also mitigates arcing during the deposition of insulating alumina films. By increasing the pulsed voltage, the film density increases, resulting in higher optical transparency, better insulating and mechanical properties, as well as superior corrosion resistance.
期刊介绍:
Thin Solid Films is an international journal which serves scientists and engineers working in the fields of thin-film synthesis, characterization, and applications. The field of thin films, which can be defined as the confluence of materials science, surface science, and applied physics, has become an identifiable unified discipline of scientific endeavor.