Progress in multi-electron sodium vanadium phosphate cathode for emerging sodium-ion batteries

IF 33.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science Pub Date : 2024-12-21 DOI:10.1016/j.pmatsci.2024.101424

Hafiz Kashif Razzaq, Chun-Chen Yang, Muhammad Norhaffis Mustafa, Arshid Numan, Mohammad Khalid

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Abstract

Sodium vanadium phosphate (NVP) has emerged as a promising cathode material for sodium-ion batteries (SIBs) due to its three-dimensional (3D) Sodium Super Ionic Conductor (NASICON) framework, which enables rapid sodium ion (Na⁺) diffusion, impressive thermal stability, and high theoretical energy density. However, the commercialization of NVP-based batteries faces challenges due to the large ionic radius of sodium (Na), which limits its electrical conductivity and structural stability. Advanced strategies have been developed to overcome these limitations, including integrating carbonaceous materials, targeted ion doping, nanosizing, and manipulating the shape and structure of NVP particles. Despite progress in Na⁺ migration pathways, synthesis, engineering, and electronic/ionic mobility improvements, an essential aspect of NVP is lacking, such as scalability, recycling, and electrolyte compatibility necessary for the commercial deployment of NVP-based sodium-ion batteries (SIBs). This review aims to fill this gap by comprehensively investigating these obstacles to delimit NVP-based SIBs. Moreover, a comparative analysis with lithium iron phosphate (LFP), a benchmark material in commercial LIBs, highlights NVP’s potential advantages in cost, safety, and Na availability. However, challenges in energy density and scalability remain. By evaluating the relationships between these factors and electrochemical performance, this review provides a comprehensive understanding of NVP-based batteries and identifies opportunities for further improvement.

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新兴钠离子电池用多电子磷酸钒钠阴极研究进展

磷酸钒钠（NVP）由于其三维（3D）钠超离子导体（NASICON）框架，使钠离子（Na+）快速扩散，令人印象深刻的热稳定性和高理论能量密度，已成为钠离子电池（sib）的一种有前途的阴极材料。然而，由于钠（Na）的离子半径大，限制了其导电性和结构稳定性，nvp基电池的商业化面临挑战。为了克服这些限制，研究人员开发了一些先进的策略，包括整合碳质材料、靶向离子掺杂、纳米化以及控制NVP颗粒的形状和结构。尽管在Na+迁移途径、合成、工程和电子/离子迁移率方面取得了进展，但NVP的一个重要方面仍然缺乏，例如NVP基钠离子电池（sib）商业部署所需的可扩展性、可回收性和电解质兼容性。本综述旨在通过全面调查这些障碍来划分基于nvp的sib来填补这一空白。此外，与商用锂离子电池的基准材料磷酸铁锂（LFP）的对比分析强调了NVP在成本、安全性和Na可用性方面的潜在优势。然而，能量密度和可扩展性方面的挑战仍然存在。通过评估这些因素与电化学性能之间的关系，本综述提供了对nvp基电池的全面了解，并确定了进一步改进的机会。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Materials Science 工程技术-材料科学：综合

CiteScore

59.60

自引率

0.80%

发文量

101

审稿时长

11.4 months

期刊介绍： Progress in Materials Science is a journal that publishes authoritative and critical reviews of recent advances in the science of materials. The focus of the journal is on the fundamental aspects of materials science, particularly those concerning microstructure and nanostructure and their relationship to properties. Emphasis is also placed on the thermodynamics, kinetics, mechanisms, and modeling of processes within materials, as well as the understanding of material properties in engineering and other applications. The journal welcomes reviews from authors who are active leaders in the field of materials science and have a strong scientific track record. Materials of interest include metallic, ceramic, polymeric, biological, medical, and composite materials in all forms. Manuscripts submitted to Progress in Materials Science are generally longer than those found in other research journals. While the focus is on invited reviews, interested authors may submit a proposal for consideration. Non-invited manuscripts are required to be preceded by the submission of a proposal. Authors publishing in Progress in Materials Science have the option to publish their research via subscription or open access. Open access publication requires the author or research funder to meet a publication fee (APC). Abstracting and indexing services for Progress in Materials Science include Current Contents, Science Citation Index Expanded, Materials Science Citation Index, Chemical Abstracts, Engineering Index, INSPEC, and Scopus.