Rasha I. Anayah, Brian G. Diamond, Christopher H. Hendon and V. Sara Thoi
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引用次数: 0
Abstract
We synthesize and study the charge transfer properties of a oligosilyl coordination polymer formed from zirconium clusters. Although the product lacks long range order, spectroscopic and computational evidence suggest that the metal–ligand bond is formed, and the principle crystallographic reflections closely match those simulated from inter-node spacings matching that of the ligand. The porous polymer allows for the incorporation of guest molecules as demonstrated by the intercalation of 7,7,8,8-tetracyanoquinodimethane (TCNQ). Charge transfer is predicted from DFT and experimentally observed by infrared spectroscopy, solid-state 29Si nuclear magnetic spectroscopy, and voltammetry.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors