A reassessment of 5f occupation in plutonium

IF 1.8 4区 物理与天体物理 Q2 SPECTROSCOPY
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引用次数: 0

Abstract

A detailed spectroscopic simulation of the original Pu N4,5 and O4,5 X-Ray Absorption Spectroscopy (XAS) has been performed. Additionally, a fundamental flaw in the Electron Energy Loss Spectroscopy (EELS) measurement has been corrected. Thus, the determination of the 5f occupation (n) in elemental Pu has been re-evaluated with the result that n = 5.0 ± 0.1 for αPu and n = 4.9 ± 0.2 for δPu. These values are significantly lower than the value of ∼5½ that was propagated earlier.

对钚中 5f 占位的重新评估
对原始钚 N4,5 和 O4,5 X 射线吸收光谱(XAS)进行了详细的光谱模拟。此外,还纠正了电子能量损失光谱(EELS)测量中的一个基本缺陷。因此,对元素钚中 5f 占位 (n) 的测定进行了重新评估,结果是 αPu 的 n = 5.0 ± 0.1,δPu 的 n = 4.9 ± 0.2。这些数值明显低于先前传播的 ∼5½ 值。
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来源期刊
CiteScore
3.30
自引率
5.30%
发文量
64
审稿时长
60 days
期刊介绍: The Journal of Electron Spectroscopy and Related Phenomena publishes experimental, theoretical and applied work in the field of electron spectroscopy and electronic structure, involving techniques which use high energy photons (>10 eV) or electrons as probes or detected particles in the investigation.
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