{"title":"A Biphasic Plasma Microreactor for Pollutants Degradation in Water","authors":"Ghewa Akiki, Stephanie Ognier, Pascal Rajagopalan, Cecilia Devaux, Ichiro Kano, Noelia Merino, Simeon Cavadias, Yann Ratieuville, Xavier Duten, Michael Tatoulian","doi":"10.1007/s11090-024-10503-6","DOIUrl":null,"url":null,"abstract":"<div><p>The combination of plasma technology with microfluidics has gained significant attention in recent years. The unique characteristics of microfluidic chips, such as high surface-to-volume ratio and efficient mass transfer, coupled with plasma’s ability to provide the necessary green energy for the degradation of complex molecules, make this combination promising for water and wastewater treatment applications. A gas/liquid biphasic dielectric barrier discharge (DBD) plasma microreactor powered by a nano-pulsed excitation source, at atmospheric pressure, was used to study the degradation of p-benzoquinone and caffeine in water, chosen as model molecules for water pollution. Based on High Performance Liquid Chromatography (HPLC) analyses, the argon plasma was able to completely degrade both molecules at concentrations 10<sup>− 5</sup>, 10<sup>− 4</sup> and 10<sup>− 3</sup> mol/L. At higher concentration (10<sup>− 2</sup> mol/L), the plasma promotes the synthesis of hydroquinone from p-benzoquinone. A 50% mineralization is achieved after plasma for the caffeine in aqueous solution at 10<sup>− 5</sup> M.</p></div>","PeriodicalId":734,"journal":{"name":"Plasma Chemistry and Plasma Processing","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasma Chemistry and Plasma Processing","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11090-024-10503-6","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The combination of plasma technology with microfluidics has gained significant attention in recent years. The unique characteristics of microfluidic chips, such as high surface-to-volume ratio and efficient mass transfer, coupled with plasma’s ability to provide the necessary green energy for the degradation of complex molecules, make this combination promising for water and wastewater treatment applications. A gas/liquid biphasic dielectric barrier discharge (DBD) plasma microreactor powered by a nano-pulsed excitation source, at atmospheric pressure, was used to study the degradation of p-benzoquinone and caffeine in water, chosen as model molecules for water pollution. Based on High Performance Liquid Chromatography (HPLC) analyses, the argon plasma was able to completely degrade both molecules at concentrations 10− 5, 10− 4 and 10− 3 mol/L. At higher concentration (10− 2 mol/L), the plasma promotes the synthesis of hydroquinone from p-benzoquinone. A 50% mineralization is achieved after plasma for the caffeine in aqueous solution at 10− 5 M.
期刊介绍:
Publishing original papers on fundamental and applied research in plasma chemistry and plasma processing, the scope of this journal includes processing plasmas ranging from non-thermal plasmas to thermal plasmas, and fundamental plasma studies as well as studies of specific plasma applications. Such applications include but are not limited to plasma catalysis, environmental processing including treatment of liquids and gases, biological applications of plasmas including plasma medicine and agriculture, surface modification and deposition, powder and nanostructure synthesis, energy applications including plasma combustion and reforming, resource recovery, coupling of plasmas and electrochemistry, and plasma etching. Studies of chemical kinetics in plasmas, and the interactions of plasmas with surfaces are also solicited. It is essential that submissions include substantial consideration of the role of the plasma, for example, the relevant plasma chemistry, plasma physics or plasma–surface interactions; manuscripts that consider solely the properties of materials or substances processed using a plasma are not within the journal’s scope.