{"title":"The Impact of Melt Transparency on Li2MoO4 Single Crystal Growth by the Czochralski Technique","authors":"Yahia Zakarya Bouzouaoui, Rayane Ayadi, Oumaima Brakni, Samir Zermout, Idir Lasloudji, Matias Velázquez","doi":"10.1002/crat.202400095","DOIUrl":null,"url":null,"abstract":"<p>In this paper, it is found that taking a semitransparent melt, influences c–m interface shape, heat transfer, melt flow and von Mises thermal stress distributions, therefore the quality of the grown crystal. As a result, when absorption coefficients of both melt and crystal change from transparent to opaque case, the c–m interface convexity reduces from 12.5 to 5.8 mm, its shape becomes more convex toward the melt, and the maximum von Mises thermal stresses decreases from 69.55 to 13.8 MPa. For the second study, where the crystal absorption coefficient is fixed at <span></span><math>\n <semantics>\n <mrow>\n <mn>20</mn>\n <mspace></mspace>\n <msup>\n <mi>m</mi>\n <mrow>\n <mo>−</mo>\n <mn>1</mn>\n </mrow>\n </msup>\n </mrow>\n <annotation>$20\\ {{\\mathrm{m}}}^{ - 1}$</annotation>\n </semantics></math>, the c–m interface convexity increases with the increase in melt absorption coefficient. The maximum and minimum von Mises stresses for the case <span></span><math>\n <semantics>\n <mrow>\n <mn>100</mn>\n <mspace></mspace>\n <msup>\n <mi>m</mi>\n <mrow>\n <mo>−</mo>\n <mn>1</mn>\n </mrow>\n </msup>\n </mrow>\n <annotation>$100\\ {{\\mathrm{m}}}^{ - 1}$</annotation>\n </semantics></math> are low compared to other values; then the grown crystal has a good quality.</p>","PeriodicalId":48935,"journal":{"name":"Crystal Research and Technology","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Research and Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/crat.202400095","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 0
Abstract
In this paper, it is found that taking a semitransparent melt, influences c–m interface shape, heat transfer, melt flow and von Mises thermal stress distributions, therefore the quality of the grown crystal. As a result, when absorption coefficients of both melt and crystal change from transparent to opaque case, the c–m interface convexity reduces from 12.5 to 5.8 mm, its shape becomes more convex toward the melt, and the maximum von Mises thermal stresses decreases from 69.55 to 13.8 MPa. For the second study, where the crystal absorption coefficient is fixed at , the c–m interface convexity increases with the increase in melt absorption coefficient. The maximum and minimum von Mises stresses for the case are low compared to other values; then the grown crystal has a good quality.
期刊介绍:
The journal Crystal Research and Technology is a pure online Journal (since 2012).
Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of
-crystal growth techniques and phenomena (including bulk growth, thin films)
-modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals)
-industrial crystallisation
-application of crystals in materials science, electronics, data storage, and optics
-experimental, simulation and theoretical studies of the structural properties of crystals
-crystallographic computing