Influence of amorphous zinc oxide on structural changes in a gold nanolayer after annealing

IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS
Petro Lytvyn, Olexandr Gudimenko, Volodymyr Maslov, Andrii Korchovyi, Natalia Kachur
{"title":"Influence of amorphous zinc oxide on structural changes in a gold nanolayer after annealing","authors":"Petro Lytvyn,&nbsp;Olexandr Gudimenko,&nbsp;Volodymyr Maslov,&nbsp;Andrii Korchovyi,&nbsp;Natalia Kachur","doi":"10.1016/j.tsf.2024.140518","DOIUrl":null,"url":null,"abstract":"<div><p>This study aimed to investigate the impact of an amorphous zinc oxide nanolayer, approximately 5 nm thick, on the results of surface plasmon resonance measurements of the air refractive index and to assess structural changes in the underlying gold nanolayer before and after annealing. We compared the properties of the samples after annealing under two conditions: one with only the gold nanolayer in its as-deposited state on the substrate, and another with an additional amorphous zinc oxide nanolayer on top. The findings revealed that during the concurrent formation of zinc oxide via sol-gel technology on gold nanofilms and annealing at 773 K for 30 min, the zinc oxide formed an amorphous film with a thickness of 5 nm. This layer effectively protected the gold from oxidation and significantly reduced microdeformation levels from 1.51 % to 0.005 %. The surface roughness of this film was measured at 5 Å.</p></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"806 ","pages":"Article 140518"},"PeriodicalIF":2.0000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thin Solid Films","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040609024003195","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0

Abstract

This study aimed to investigate the impact of an amorphous zinc oxide nanolayer, approximately 5 nm thick, on the results of surface plasmon resonance measurements of the air refractive index and to assess structural changes in the underlying gold nanolayer before and after annealing. We compared the properties of the samples after annealing under two conditions: one with only the gold nanolayer in its as-deposited state on the substrate, and another with an additional amorphous zinc oxide nanolayer on top. The findings revealed that during the concurrent formation of zinc oxide via sol-gel technology on gold nanofilms and annealing at 773 K for 30 min, the zinc oxide formed an amorphous film with a thickness of 5 nm. This layer effectively protected the gold from oxidation and significantly reduced microdeformation levels from 1.51 % to 0.005 %. The surface roughness of this film was measured at 5 Å.

无定形氧化锌对退火后金纳米层结构变化的影响
本研究旨在探讨厚度约为 5 纳米的无定形氧化锌纳米层对空气折射率表面等离子共振测量结果的影响,并评估退火前后底层金纳米层的结构变化。我们比较了样品在两种条件下退火后的特性:一种是基底上仅有金纳米层的沉积状态,另一种是基底上有额外的无定形氧化锌纳米层。研究结果表明,在金纳米薄膜上通过溶胶-凝胶技术同时形成氧化锌并在 773 K 下退火 30 分钟的过程中,氧化锌形成了一层厚度为 5 纳米的无定形薄膜。这层膜有效地保护了金免受氧化,并将微变形水平从 1.51 % 显著降至 0.005 %。经测量,该薄膜的表面粗糙度为 5 Å。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Thin Solid Films
Thin Solid Films 工程技术-材料科学:膜
CiteScore
4.00
自引率
4.80%
发文量
381
审稿时长
7.5 months
期刊介绍: Thin Solid Films is an international journal which serves scientists and engineers working in the fields of thin-film synthesis, characterization, and applications. The field of thin films, which can be defined as the confluence of materials science, surface science, and applied physics, has become an identifiable unified discipline of scientific endeavor.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信