Enhancing performance of lower-temperature solid oxide fuel cell cathodes through surface engineering

IF 33.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Halefom G. Desta , Gebrehiwot Gebreslassie , Jianjian Zhang , Bin Lin , Yun Zheng , Jiujun Zhang
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Abstract

Solid oxide fuel cells (SOFCs) are recognized as highly efficient energy-conversion and eco-friendliness technologies. However, the high-temperature operation of conventional SOFCs at 800–1000 °C has hindered their practical applications due to the accelerated materials degradation and the resulting performance failures. Therefore, developing lower-temperature SOFCs (LT-SOFCs) seems necessary. With respect to LT-SOFCs, developing highly active cathode materials with long-term stability has been identified to be the priority, where cathode surface engineering has surfaced as a pivotal technique to bolster cathode functionality. This review delves into the myriads of surface modification strategies, including solution infiltration, atomic layer deposition (ALD), one-pot method, exsolution, pulsed laser deposition (PLD), and electrospinning (ES). Each method is scrutinized for its potential to enhance the cathode oxygen reduction reaction (ORR), a critical process in LT-SOFCs, while also fortifying the structural stability of cathode materials. This paper also meticulously evaluates recent breakthroughs in cathode surface engineering with highlighting the nuanced interplay between microstructural features and electrochemical performance. The technical challenges that persist in the practical application of LT-SOFCs are analyzed in this work and the possible further research directions are also suggested for overcoming the challenges towards significantly improved cathode performance including activity and stability.

Abstract Image

通过表面工程提高低温固体氧化物燃料电池阴极的性能
固体氧化物燃料电池(SOFC)是公认的高效能源转换和环保技术。然而,传统 SOFC 在 800-1000 °C 高温下运行会加速材料降解并导致性能失效,从而阻碍了其实际应用。因此,开发低温 SOFC(LT-SOFC)似乎很有必要。关于 LT-SOFC,开发具有长期稳定性的高活性阴极材料已被确定为当务之急,其中阴极表面工程已成为增强阴极功能的关键技术。本综述深入探讨了各种表面改性策略,包括溶液渗透、原子层沉积(ALD)、一锅法、外溶法、脉冲激光沉积(PLD)和电纺丝(ES)。本文仔细研究了每种方法在增强阴极氧还原反应(ORR)(LT-SOFCs 的关键过程)方面的潜力,同时还加强了阴极材料的结构稳定性。本文还细致评估了阴极表面工程的最新突破,强调了微观结构特征与电化学性能之间微妙的相互作用。本文分析了 LT-SOFC 在实际应用中面临的技术挑战,并提出了可能的进一步研究方向,以克服挑战,显著提高阴极的性能,包括活性和稳定性。
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来源期刊
Progress in Materials Science
Progress in Materials Science 工程技术-材料科学:综合
CiteScore
59.60
自引率
0.80%
发文量
101
审稿时长
11.4 months
期刊介绍: Progress in Materials Science is a journal that publishes authoritative and critical reviews of recent advances in the science of materials. The focus of the journal is on the fundamental aspects of materials science, particularly those concerning microstructure and nanostructure and their relationship to properties. Emphasis is also placed on the thermodynamics, kinetics, mechanisms, and modeling of processes within materials, as well as the understanding of material properties in engineering and other applications. The journal welcomes reviews from authors who are active leaders in the field of materials science and have a strong scientific track record. Materials of interest include metallic, ceramic, polymeric, biological, medical, and composite materials in all forms. Manuscripts submitted to Progress in Materials Science are generally longer than those found in other research journals. While the focus is on invited reviews, interested authors may submit a proposal for consideration. Non-invited manuscripts are required to be preceded by the submission of a proposal. Authors publishing in Progress in Materials Science have the option to publish their research via subscription or open access. Open access publication requires the author or research funder to meet a publication fee (APC). Abstracting and indexing services for Progress in Materials Science include Current Contents, Science Citation Index Expanded, Materials Science Citation Index, Chemical Abstracts, Engineering Index, INSPEC, and Scopus.
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