Ar-O2 Plasma-Induced Grafting of Quaternary Ammonium on Polyvinyl Chloride Surface to Improve its Antimicrobial Properties

IF 2.6 3区 物理与天体物理 Q3 ENGINEERING, CHEMICAL
Sui Siyuan, Ni Guohua, Sun Hongmei, Kong Ling, Sun Tao
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Abstract

In this paper, a novel method is presented to enhance the antimicrobial properties of polyvinyl chloride (PVC) via plasma-induced grafting of quaternary ammonium (QA). The results show that the content of oxygen-containing functional groups on PVC surface is significantly increased after Ar-O2 plasma treatment, beneficially enhancing the thickness and adhesion of QA coating. Plasma treatment time critically affects the morphology of PVC surface, which is closely related to the number, depth and diameter of pit on the surface. With the increase of pits size, the PVC surface forms ridge-like protrusions. The coating formed by grafting QA maintains the morphology characteristics of plasma-treated PVC surface. Results of antibacterial test show that specimens have the best antibacterial activity when there are a high and sharp ridge-like structure of QA coating on the plasma-treated PVC surface.

Abstract Image

Ar-O2 等离子体诱导季铵在聚氯乙烯表面接枝以改善其抗菌性能
本文提出了一种通过等离子体诱导接枝季铵(QA)来增强聚氯乙烯(PVC)抗菌性能的新方法。结果表明,经过 Ar-O2 等离子处理后,聚氯乙烯表面含氧官能团的含量显著增加,有利于增强 QA 涂层的厚度和附着力。等离子处理时间对聚氯乙烯表面的形态有重要影响,这与表面凹坑的数量、深度和直径密切相关。随着凹坑尺寸的增大,PVC 表面会形成脊状突起。接枝 QA 形成的涂层保持了等离子处理过的 PVC 表面的形态特征。抗菌测试结果表明,当等离子处理过的 PVC 表面上的 QA 涂层具有高而尖锐的脊状结构时,试样的抗菌活性最佳。
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来源期刊
Plasma Chemistry and Plasma Processing
Plasma Chemistry and Plasma Processing 工程技术-工程:化工
CiteScore
5.90
自引率
8.30%
发文量
73
审稿时长
6-12 weeks
期刊介绍: Publishing original papers on fundamental and applied research in plasma chemistry and plasma processing, the scope of this journal includes processing plasmas ranging from non-thermal plasmas to thermal plasmas, and fundamental plasma studies as well as studies of specific plasma applications. Such applications include but are not limited to plasma catalysis, environmental processing including treatment of liquids and gases, biological applications of plasmas including plasma medicine and agriculture, surface modification and deposition, powder and nanostructure synthesis, energy applications including plasma combustion and reforming, resource recovery, coupling of plasmas and electrochemistry, and plasma etching. Studies of chemical kinetics in plasmas, and the interactions of plasmas with surfaces are also solicited. It is essential that submissions include substantial consideration of the role of the plasma, for example, the relevant plasma chemistry, plasma physics or plasma–surface interactions; manuscripts that consider solely the properties of materials or substances processed using a plasma are not within the journal’s scope.
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