Phenolic, volatile compounds, antioxidant, and preservative activity of Argentinian Kabuli chickpea husk extract

IF 1.9 4区农林科学 Q3 CHEMISTRY, APPLIED

Journal of the American Oil Chemists Society Pub Date : 2023-10-18 DOI:10.1002/aocs.12759

Ornella F. Camiletti, Antonella E. Bergesse, María C. Prieto, Patricia R. Quiroga, Gonzalo A. Ojeda, Sonia Sgroppo, Cecilia G. Riveros, Nelson R. Grosso

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Abstract

The objective of this study was to analyze the chemical composition and antioxidant activity of a chickpea husk polyphenol extract (CPE) obtained from Argentinian Kabuli chickpea and to evaluate its antioxidant effect on the chemical quality of sunflower oil. The polyphenol composition of CPE was analyzed by HPLC–ESI-MS/MS. Antioxidant activity was evaluated by DPPH•, FRAP, ABTS•+, and chelating activity in ferrous ion tests. An accelerated oxidation test in sunflower oil was carried out by applying 0.01, 0.02, and 0.05% p/p CPE and comparing it with BHT (0.02%). Peroxide value, conjugated dienes, and volatile compounds were determined on sunflower oil samples. Twelve polyphenols were identified in the chickpea extract. The CPE showed in vitro antioxidant activity. The lowest doses (0.01% and 0.02%) protected sunflower oil more efficiently against oxidative deterioration than the higher level (0.05%). Chickpea husk extract has a good antioxidant effect on sunflower oil, which helps to preserve the quality properties of this product.

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阿根廷卡布利鹰嘴豆壳提取物的酚类、挥发性化合物、抗氧化剂和防腐剂活性

本研究旨在分析从阿根廷卡布利鹰嘴豆中提取的鹰嘴豆壳多酚提取物（CPE）的化学成分和抗氧化活性，并评估其对葵花籽油化学质量的抗氧化作用。采用 HPLC-ESI-MS/MS 分析了 CPE 中的多酚成分。抗氧化活性通过 DPPH-、FRAP、ABTS-+ 和亚铁离子螯合活性测试进行评估。通过使用 0.01%、0.02% 和 0.05% p/p CPE 在葵花籽油中进行加速氧化试验，并与 BHT（0.02%）进行比较。测定了葵花籽油样品的过氧化值、共轭二烯和挥发性化合物。在鹰嘴豆提取物中发现了 12 种多酚。鹰嘴豆提取物具有体外抗氧化活性。最低剂量（0.01% 和 0.02%）比高剂量（0.05%）能更有效地防止葵花籽油氧化变质。鹰嘴豆壳提取物对葵花籽油具有良好的抗氧化作用，有助于保持这种产品的质量特性。

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来源期刊

Journal of the American Oil Chemists Society 工程技术-食品科技

CiteScore

4.10

自引率

5.00%

发文量

审稿时长

2.4 months

期刊介绍： The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate. JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of yeartoyear, environmental, and/ or cultivar variations through use of appropriate statistical analyses.