Defect control in epoxy dry film with improved electric performances

S. Luo, Chunbo Gao, Liqiang Cao, Shuhui Yu, Junyi Yu, Fengwei Dai, R. Sun, C. Wong
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Abstract

Advanced adhesive film materials, such as embedded capacitor materials, insulating built-up films, underfill films, die attach films and etc, which have the superiorities of flexibility, controllable thickness, large size, and easy processing, have been widely used in electronic packaging. The reliability of electronic devices is directly related to the internal defects existing in the materials. Under high temperature and high electric field, the space charges in the polymer will accumulate at the interface around the defect. When the density of charge carriers approaches a critical value, the electric components will be brokendown. Herein, we try to prevent the formation of defects like pores and pits in epoxy based composite films and the relevant mechanism is investigated. The surface morphology of the films is modified by adding a defoamer and a leveling agent. The defoamer agent can assist the breakage and elimination of bubbles. The leveling agent can improve the flowability of the half-dry film and then fill the pits formed after the breakage of bubbles. The effect of defects on the Weibull distribution of electric breakdown strength of the epoxy composite films has been analyzed. It proves that high electric breakdown strength can be achieved on the film with improved surface morphology. This study gives a guide for designing high quality epoxy films with improved electrical performance.
改善环氧干膜电性能的缺陷控制
先进的粘接薄膜材料,如嵌入式电容器材料、绝缘堆积膜、下填充膜、贴模膜等,具有柔性强、厚度可控、尺寸大、加工方便等优点,在电子封装中得到了广泛的应用。电子器件的可靠性与材料内部存在的缺陷直接相关。在高温和高电场作用下,聚合物中的空间电荷会在缺陷周围的界面处积聚。当载流子密度接近某一临界值时,电气元件将发生击穿。在此,我们试图防止环氧基复合膜中气孔和凹坑等缺陷的形成,并对其机理进行了研究。通过添加消泡剂和流平剂来改变薄膜的表面形貌。消泡剂可以帮助破裂和消除气泡。流平剂可以改善半干膜的流动性,然后填充气泡破裂后形成的凹坑。分析了缺陷对环氧复合薄膜电击穿强度威布尔分布的影响。结果表明,通过改善膜的表面形貌可以获得较高的电击穿强度。该研究为设计高质量、高电性能的环氧树脂薄膜提供了指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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