Forming of SiO2 film by spin-on glass and CO2 laser annealing for gate insulator of polycrystalline silicon thin film transistors

Daisuke Hishitani, M. Horita, Y. Ishikawa, H. Ikenoue, Yosuke Watanabe, Y. Uraoka
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Abstract

CO2 laser was irradiated to per-hydro-polysilazane by us. Per-hydro-polysilazane as SiO2 precursor was spin-coated on the polycrystalline silicon substrate. CO2 laser was irradiated after prebaking Per-hydro-polysilazane film. Atomic force microscope analysis showed that the film after CO2 laser irradiation was formed flatly. Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and secondary ion mass spectrometry analysis showed that uniform SiO2 film in the depth direction was obtained by CO2 Laser Annealing compared with conventional furnace annealing.
多晶硅薄膜晶体管栅极绝缘子用自旋玻璃和CO2激光退火制备SiO2薄膜
用CO2激光辐照过氢聚硅氮烷。将过氢聚硅氮烷作为SiO2前驱体自旋涂覆在多晶硅衬底上。采用CO2激光照射预焙过氢聚硅氮烷膜。原子力显微镜分析表明,CO2激光辐照后薄膜形成平整。傅里叶变换红外光谱、x射线光电子能谱和二次离子质谱分析表明,与常规炉退火相比,CO2激光退火在深度方向上获得了均匀的SiO2薄膜。
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