Time-of-Flight Secondary Ion Mass Spectrometry profiling for arsenic in silicon dioxide matrix

H. Teo, Yun Wang, Z. Mo, S. Zhao
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Abstract

This paper showed that 75As was a better analyte species than 28Si75As in silicon dioxide for accurate quantitative profiling by Time-Of-Flight Secondary Ion Mass Spectrometry. Contrary to silicon matrix, the ion yield of 75As showed 1 order higher than 28Si 75As in silicon dioxide matrix. The average RSF for 75As in silicon dioxide was determined to be 5.62E20 and lower variation of 75As RSF was observed.
二氧化硅基体中砷的飞行时间二次离子质谱分析
结果表明,在二氧化硅中,75As比28Si75As更适合于飞行时间二次离子质谱法的精确定量分析。与硅基体相反,在二氧化硅基体中,75As的离子产率比28Si 75As高出1个数量级。测定了二氧化硅中75As的平均RSF为5.62E20,并且观察到75As RSF的变化较小。
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