{"title":"太阳能利用与转化用卟啉/g-C3N4复合光催化剂研究进展","authors":"Sudi Chen, Jiajia Wei, Xitong Ren, Keke Song, Jiajie Sun, Feng Bai, Shufang Tian","doi":"10.3390/molecules28114283","DOIUrl":null,"url":null,"abstract":"<p><p>Transforming solar energy into chemical bonds is a promising and viable way to store solar energy. Porphyrins are natural light-capturing antennas, and graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>) is an effective, artificially synthesized organic semiconductor. Their excellent complementarity has led to a growing number of research papers on porphyrin/g-C<sub>3</sub>N<sub>4</sub> hybrids for solar energy utilization. This review highlights the recent progress in porphyrin/g-C<sub>3</sub>N<sub>4</sub> composites, including: (1) porphyrin molecules/g-C<sub>3</sub>N<sub>4</sub> composite photocatalysts connected via noncovalent or covalent interactions, and (2) porphyrin-based nanomaterials/g-C<sub>3</sub>N<sub>4</sub> composite photocatalysts, such as porphyrin-based MOF/g-C<sub>3</sub>N<sub>4</sub>, porphyrin-based COF/g-C<sub>3</sub>N<sub>4</sub>, and porphyrin-based assembly/g-C<sub>3</sub>N<sub>4</sub> heterojunction nanostructures. Additionally, the review discusses the versatile applications of these composites, including artificial photosynthesis for hydrogen evolution, CO<sub>2</sub> reduction, and pollutant degradation. Lastly, critical summaries and perspectives on the challenges and future directions in this field are also provided.</p>","PeriodicalId":19041,"journal":{"name":"Molecules","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2023-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254224/pdf/","citationCount":"4","resultStr":"{\"title\":\"Recent Progress in Porphyrin/g-C<sub>3</sub>N<sub>4</sub> Composite Photocatalysts for Solar Energy Utilization and Conversion.\",\"authors\":\"Sudi Chen, Jiajia Wei, Xitong Ren, Keke Song, Jiajie Sun, Feng Bai, Shufang Tian\",\"doi\":\"10.3390/molecules28114283\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Transforming solar energy into chemical bonds is a promising and viable way to store solar energy. Porphyrins are natural light-capturing antennas, and graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>) is an effective, artificially synthesized organic semiconductor. Their excellent complementarity has led to a growing number of research papers on porphyrin/g-C<sub>3</sub>N<sub>4</sub> hybrids for solar energy utilization. This review highlights the recent progress in porphyrin/g-C<sub>3</sub>N<sub>4</sub> composites, including: (1) porphyrin molecules/g-C<sub>3</sub>N<sub>4</sub> composite photocatalysts connected via noncovalent or covalent interactions, and (2) porphyrin-based nanomaterials/g-C<sub>3</sub>N<sub>4</sub> composite photocatalysts, such as porphyrin-based MOF/g-C<sub>3</sub>N<sub>4</sub>, porphyrin-based COF/g-C<sub>3</sub>N<sub>4</sub>, and porphyrin-based assembly/g-C<sub>3</sub>N<sub>4</sub> heterojunction nanostructures. Additionally, the review discusses the versatile applications of these composites, including artificial photosynthesis for hydrogen evolution, CO<sub>2</sub> reduction, and pollutant degradation. Lastly, critical summaries and perspectives on the challenges and future directions in this field are also provided.</p>\",\"PeriodicalId\":19041,\"journal\":{\"name\":\"Molecules\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2023-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254224/pdf/\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.3390/molecules28114283\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3390/molecules28114283","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
Recent Progress in Porphyrin/g-C3N4 Composite Photocatalysts for Solar Energy Utilization and Conversion.
Transforming solar energy into chemical bonds is a promising and viable way to store solar energy. Porphyrins are natural light-capturing antennas, and graphitic carbon nitride (g-C3N4) is an effective, artificially synthesized organic semiconductor. Their excellent complementarity has led to a growing number of research papers on porphyrin/g-C3N4 hybrids for solar energy utilization. This review highlights the recent progress in porphyrin/g-C3N4 composites, including: (1) porphyrin molecules/g-C3N4 composite photocatalysts connected via noncovalent or covalent interactions, and (2) porphyrin-based nanomaterials/g-C3N4 composite photocatalysts, such as porphyrin-based MOF/g-C3N4, porphyrin-based COF/g-C3N4, and porphyrin-based assembly/g-C3N4 heterojunction nanostructures. Additionally, the review discusses the versatile applications of these composites, including artificial photosynthesis for hydrogen evolution, CO2 reduction, and pollutant degradation. Lastly, critical summaries and perspectives on the challenges and future directions in this field are also provided.
期刊介绍:
Molecules (ISSN 1420-3049, CODEN: MOLEFW) is an open access journal of synthetic organic chemistry and natural product chemistry. All articles are peer-reviewed and published continously upon acceptance. Molecules is published by MDPI, Basel, Switzerland. Our aim is to encourage chemists to publish as much as possible their experimental detail, particularly synthetic procedures and characterization information. There is no restriction on the length of the experimental section. In addition, availability of compound samples is published and considered as important information. Authors are encouraged to register or deposit their chemical samples through the non-profit international organization Molecular Diversity Preservation International (MDPI). Molecules has been launched in 1996 to preserve and exploit molecular diversity of both, chemical information and chemical substances.