常压等离子体合成金纳米粒子/碳纳米管光热转换杂化体

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Daye Sun, James McLaughlan, Li Zhang, Brian G. Falzon, Davide Mariotti, Paul Maguire, Dan Sun*
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引用次数: 21

摘要

本文首次在室温常压直流等离子体条件下,在水溶液中一步合成了金纳米颗粒/羧基功能化碳纳米管(AuNP/CNT-COOH)纳米杂化体。在不使用还原剂或表面活性剂的情况下,在CNT-COOH表面形成均匀分布的aunp。通过改变金盐前驱体的浓度,可以调节AuNP的大小。UV-vis、ζ-电位和x射线光电子能谱表明,CNTs上的羧基表面官能团是AuNPs的成核和生长位点,并详细阐明了等离子体化学诱导的多种潜在反应途径。纳米杂化材料表现出显著增强的拉曼散射和光热转换效率。这对潜在的多模式癌症治疗应用至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Atmospheric Pressure Plasma-Synthesized Gold Nanoparticle/Carbon Nanotube Hybrids for Photothermal Conversion

Atmospheric Pressure Plasma-Synthesized Gold Nanoparticle/Carbon Nanotube Hybrids for Photothermal Conversion

In this work, a room-temperature atmospheric pressure direct-current plasma has been deployed for the one-step synthesis of gold nanoparticle/carboxyl group-functionalized carbon nanotube (AuNP/CNT-COOH) nanohybrids in aqueous solution for the first time. Uniformly distributed AuNPs are formed on the surface of CNT-COOH, without the use of reducing agents or surfactants. The size of the AuNP can be tuned by changing the gold salt precursor concentration. UV–vis, ζ-potential, and X-ray photoelectron spectroscopy suggest that carboxyl surface functional groups on CNTs served as nucleation and growth sites for AuNPs and the multiple potential reaction pathways induced by the plasma chemistry have been elucidated in detail. The nanohybrids exhibit significantly enhanced Raman scattering and photothermal conversion efficiency?that are essential for potential multimodal cancer treatment applications.

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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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