有机化学产品的电化学制造路线。

IF 7.6 2区 工程技术 Q1 CHEMISTRY, APPLIED
Ricardo Mathison, Alexandra L Ramos Figueroa, Casey Bloomquist, Miguel A Modestino
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引用次数: 0

摘要

有机化学产品的电化学合成为传统热化学生产提供了一种替代方法,可直接利用可再生电力减少化学工业的温室气体排放。我们讨论了利用丰富的碳原料生产最大石化前体和基本有机化学产品(轻烯烃、烯烃氧化衍生物、芳烃和甲醇)的电化学合成方法。首先,我们确定了电化学生产每种商品的可行路线,同时考虑了反应热力学、可用原料和竞争性热化学工艺。接下来,我们总结了成功的催化和反应工程方法,以克服阻碍电化学路线以高生产率、高选择性、高稳定性和高能量转换效率运行的技术挑战。最后,我们对实现大规模电化学生产主要有机化学产品所必须实施的战略进行了展望。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrochemical Manufacturing Routes for Organic Chemical Commodities.

Electrochemical synthesis of organic chemical commodities provides an alternative to conventional thermochemical manufacturing and enables the direct use of renewable electricity to reduce greenhouse gas emissions from the chemical industry. We discuss electrochemical synthesis approaches that use abundant carbon feedstocks for the production of the largest petrochemical precursors and basic organic chemical products: light olefins, olefin oxidation derivatives, aromatics, and methanol. First, we identify feasible routes for the electrochemical production of each commodity while considering the reaction thermodynamics, available feedstocks, and competing thermochemical processes. Next, we summarize successful catalysis and reaction engineering approaches to overcome technological challenges that prevent electrochemical routes from operating at high production rates, selectivity, stability, and energy conversion efficiency. Finally, we provide an outlook on the strategies that must be implemented to achieve large-scale electrochemical manufacturing of major organic chemical commodities.

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来源期刊
Annual review of chemical and biomolecular engineering
Annual review of chemical and biomolecular engineering CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
16.00
自引率
0.00%
发文量
25
期刊介绍: The Annual Review of Chemical and Biomolecular Engineering aims to provide a perspective on the broad field of chemical (and related) engineering. The journal draws from disciplines as diverse as biology, physics, and engineering, with development of chemical products and processes as the unifying theme.
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