氧化苯酚偶联在天然产物全合成中的研究进展。

IF 12.7 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

ACS Central Science Pub Date : 2024-02-21 DOI:10.1039/d3np00009e

Matthew C. Carson , Marisa C. Kozlowski

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引用次数: 0

摘要

综述了氧化苯酚偶联在天然产物全合成中的应用。本文综述了催化和电化学方法，并与化学计量学和酶学系统进行了简要比较，评估了它们的实用性、原子经济性和其他措施。将讨论C-C和C-O氧化苯酚偶联以及烯基苯酚偶联形成的天然产物。此外，还将对苯酚和其他相关物质(咔唑、吲哚、芳醚等)的催化氧化偶联进行探索。还将评估这一特定研究领域的未来方向。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent advances in oxidative phenol coupling for the total synthesis of natural products

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Recent advances in oxidative phenol coupling for the total synthesis of natural products

Covering: 2008 to 2023

This review will describe oxidative phenol coupling as applied in the total synthesis of natural products. This review covers catalytic and electrochemical methods with a brief comparison to stoichiometric and enzymatic systems assessing their practicality, atom economy, and other measures. Natural products forged by C–C and C–O oxidative phenol couplings as well as from alkenyl phenol couplings will be addressed. Additionally, exploration into catalytic oxidative coupling of phenols and other related species (carbazoles, indoles, aryl ethers, etc.) will be surveyed. Future directions of this particular area of research will also be assessed.

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来源期刊

ACS Central Science Chemical Engineering-General Chemical Engineering

CiteScore

25.50

自引率

0.50%

发文量

194

审稿时长

10 weeks

期刊介绍： ACS Central Science publishes significant primary reports on research in chemistry and allied fields where chemical approaches are pivotal. As the first fully open-access journal by the American Chemical Society, it covers compelling and important contributions to the broad chemistry and scientific community. "Central science," a term popularized nearly 40 years ago, emphasizes chemistry's central role in connecting physical and life sciences, and fundamental sciences with applied disciplines like medicine and engineering. The journal focuses on exceptional quality articles, addressing advances in fundamental chemistry and interdisciplinary research.