Duygu Osman, İbrahim Uyanık, Hamdi Mıhçıokur, Oktay Özkan
{"title":"风化聚氯乙烯微塑料吸附环丙沙星(CIP)和克拉霉素(CLA)的性能评价。","authors":"Duygu Osman, İbrahim Uyanık, Hamdi Mıhçıokur, Oktay Özkan","doi":"10.1080/10934529.2023.2198475","DOIUrl":null,"url":null,"abstract":"<p><p>The sorption kinetics of two of the most frequently used antibiotics onto recycled (weathered) polyvinyl chloride (PVC) was investigated, using Freundlich and Langmuir isotherm models. Various experimental conditions were set, including pH, contact time, rotational speed, temperature, and initial concentration. The batch experimental results indicated that Freundlich model was better fitted than Langmuir (R<sup>2</sup>: 98.7 and 84.7, for CIP and CLA respectively). Maximum adsorption capacity is 45.9 mg/g and 22.0 mg/g for CIP and CLA, respectively. Enthalpy (ΔH), and entropy (ΔS) values were negative for CIP, indicating that the reaction was exothermic and spontaneous, respectively. It was vice versa for CLA. Field emission scanning electron microscope (FESEM) and Fourier transform infrared spectrometer (FT-IR) analysis confirmed the physical adsorption mechanism. The results demonstrated that the recycled PVC microplastic has a good capacity for adsorption for both antibiotics.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Evaluation of ciprofloxacin (CIP) and clarithromycin (CLA) adsorption with weathered PVC microplastics.\",\"authors\":\"Duygu Osman, İbrahim Uyanık, Hamdi Mıhçıokur, Oktay Özkan\",\"doi\":\"10.1080/10934529.2023.2198475\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The sorption kinetics of two of the most frequently used antibiotics onto recycled (weathered) polyvinyl chloride (PVC) was investigated, using Freundlich and Langmuir isotherm models. Various experimental conditions were set, including pH, contact time, rotational speed, temperature, and initial concentration. The batch experimental results indicated that Freundlich model was better fitted than Langmuir (R<sup>2</sup>: 98.7 and 84.7, for CIP and CLA respectively). Maximum adsorption capacity is 45.9 mg/g and 22.0 mg/g for CIP and CLA, respectively. Enthalpy (ΔH), and entropy (ΔS) values were negative for CIP, indicating that the reaction was exothermic and spontaneous, respectively. It was vice versa for CLA. Field emission scanning electron microscope (FESEM) and Fourier transform infrared spectrometer (FT-IR) analysis confirmed the physical adsorption mechanism. The results demonstrated that the recycled PVC microplastic has a good capacity for adsorption for both antibiotics.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1080/10934529.2023.2198475\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1080/10934529.2023.2198475","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Evaluation of ciprofloxacin (CIP) and clarithromycin (CLA) adsorption with weathered PVC microplastics.
The sorption kinetics of two of the most frequently used antibiotics onto recycled (weathered) polyvinyl chloride (PVC) was investigated, using Freundlich and Langmuir isotherm models. Various experimental conditions were set, including pH, contact time, rotational speed, temperature, and initial concentration. The batch experimental results indicated that Freundlich model was better fitted than Langmuir (R2: 98.7 and 84.7, for CIP and CLA respectively). Maximum adsorption capacity is 45.9 mg/g and 22.0 mg/g for CIP and CLA, respectively. Enthalpy (ΔH), and entropy (ΔS) values were negative for CIP, indicating that the reaction was exothermic and spontaneous, respectively. It was vice versa for CLA. Field emission scanning electron microscope (FESEM) and Fourier transform infrared spectrometer (FT-IR) analysis confirmed the physical adsorption mechanism. The results demonstrated that the recycled PVC microplastic has a good capacity for adsorption for both antibiotics.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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