{"title":"埃及西奈西南部El Gor地区古生代沉积岩α光谱同位素比值指示:铀流动年龄的启示","authors":"Mahmoud R Khattab","doi":"10.1080/10934529.2023.2165865","DOIUrl":null,"url":null,"abstract":"<p><p>The study area is located between longitude 33° 18' 00\" - 33° 21' 00\" E and latitude 28° 59' - 29° 01' N and covers approximately 700 km<sup>2</sup>. Uranium and thorium isotopes were determined by alpha spectrometry. The activity concentrations of <sup>238</sup>U, <sup>234</sup>U and <sup>235</sup>U were ranged between 245.5 ± 8.3-465.2 ± 15.2 Bq.kg<sup>-1</sup> with an average 345.5 ± 10.4-452.5 ± 9.3 Bq.kg<sup>-1</sup> and 890.5 ± 21.3 Bq.kg<sup>-1</sup> with an average 632.3 ± 14.9-11.40 ± 0.5 Bq.kg<sup>-1</sup> and 21.50 ± 1.4 Bq.kg<sup>-1</sup>, respectively. The activity concentration of <sup>232</sup>Th, <sup>230</sup>Th and <sup>228</sup>Th were ranged between 153.1 ± 0.3-318.1 ± 2.9 Bq.kg<sup>-1</sup>, 149.5 ± 0.7-280.8 ± 2.2 Bq.kg<sup>-1</sup> and 36.9 ± 0.1-60.5 ± 0.9 Bq.kg<sup>-1</sup>. The <sup>230</sup>Th/<sup>232</sup>Th activity ratios in all samples were lower than 20, indicating that these samples have been contaminated by detrital <sup>230</sup>Th. Th/U ratio varied between 1.3 and 2.1 with an average 1.8; all values were lower than 3.5, indicated enrichment of uranium. <sup>234</sup>U/<sup>238</sup>U activity ratios that higher than unity indicates that an isotope of uranium has migrated within the rock. From the isotopes of uranium and thorium and their activity ratios, the isochron age for the collected samples was about 58.96 ka.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Alpha spectrometry isotopic ratios indications in the Paleozoic sedimentary rock of El Gor area, Southwestern Sinai, Egypt: insights on uranium mobility age.\",\"authors\":\"Mahmoud R Khattab\",\"doi\":\"10.1080/10934529.2023.2165865\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The study area is located between longitude 33° 18' 00\\\" - 33° 21' 00\\\" E and latitude 28° 59' - 29° 01' N and covers approximately 700 km<sup>2</sup>. Uranium and thorium isotopes were determined by alpha spectrometry. The activity concentrations of <sup>238</sup>U, <sup>234</sup>U and <sup>235</sup>U were ranged between 245.5 ± 8.3-465.2 ± 15.2 Bq.kg<sup>-1</sup> with an average 345.5 ± 10.4-452.5 ± 9.3 Bq.kg<sup>-1</sup> and 890.5 ± 21.3 Bq.kg<sup>-1</sup> with an average 632.3 ± 14.9-11.40 ± 0.5 Bq.kg<sup>-1</sup> and 21.50 ± 1.4 Bq.kg<sup>-1</sup>, respectively. The activity concentration of <sup>232</sup>Th, <sup>230</sup>Th and <sup>228</sup>Th were ranged between 153.1 ± 0.3-318.1 ± 2.9 Bq.kg<sup>-1</sup>, 149.5 ± 0.7-280.8 ± 2.2 Bq.kg<sup>-1</sup> and 36.9 ± 0.1-60.5 ± 0.9 Bq.kg<sup>-1</sup>. The <sup>230</sup>Th/<sup>232</sup>Th activity ratios in all samples were lower than 20, indicating that these samples have been contaminated by detrital <sup>230</sup>Th. Th/U ratio varied between 1.3 and 2.1 with an average 1.8; all values were lower than 3.5, indicated enrichment of uranium. <sup>234</sup>U/<sup>238</sup>U activity ratios that higher than unity indicates that an isotope of uranium has migrated within the rock. From the isotopes of uranium and thorium and their activity ratios, the isochron age for the collected samples was about 58.96 ka.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1080/10934529.2023.2165865\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1080/10934529.2023.2165865","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Alpha spectrometry isotopic ratios indications in the Paleozoic sedimentary rock of El Gor area, Southwestern Sinai, Egypt: insights on uranium mobility age.
The study area is located between longitude 33° 18' 00" - 33° 21' 00" E and latitude 28° 59' - 29° 01' N and covers approximately 700 km2. Uranium and thorium isotopes were determined by alpha spectrometry. The activity concentrations of 238U, 234U and 235U were ranged between 245.5 ± 8.3-465.2 ± 15.2 Bq.kg-1 with an average 345.5 ± 10.4-452.5 ± 9.3 Bq.kg-1 and 890.5 ± 21.3 Bq.kg-1 with an average 632.3 ± 14.9-11.40 ± 0.5 Bq.kg-1 and 21.50 ± 1.4 Bq.kg-1, respectively. The activity concentration of 232Th, 230Th and 228Th were ranged between 153.1 ± 0.3-318.1 ± 2.9 Bq.kg-1, 149.5 ± 0.7-280.8 ± 2.2 Bq.kg-1 and 36.9 ± 0.1-60.5 ± 0.9 Bq.kg-1. The 230Th/232Th activity ratios in all samples were lower than 20, indicating that these samples have been contaminated by detrital 230Th. Th/U ratio varied between 1.3 and 2.1 with an average 1.8; all values were lower than 3.5, indicated enrichment of uranium. 234U/238U activity ratios that higher than unity indicates that an isotope of uranium has migrated within the rock. From the isotopes of uranium and thorium and their activity ratios, the isochron age for the collected samples was about 58.96 ka.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.