Cu-ZnO纳米粒子光催化降解甲基橙

Raviraj M. Kulkarni, Ramesh S. Malladi, Manjunath S. Hanagadakar
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引用次数: 1

摘要

采用2%铜掺杂氧化锌(2% Cu-ZnO)纳米颗粒在紫外光照射下,在水介质中光催化降解纺织染料衍生物甲基橙(M.O)。采用简单廉价的化学沉淀法合成了纯氧化锌纳米粒子和铜掺杂氧化锌纳米粒子。采用x射线衍射技术(XRD)、扫描电镜(SEM)和能量色散x射线分析对制备的纯氧化锌纳米粒子和铜掺杂氧化锌纳米粒子进行了表征。制备的纳米颗粒为六方纤锌矿结构。以甲基橙(M.O.)为模型化合物,研究了2% Cu-ZnO的光催化效率。考察了不同介质pH、催化剂用量、M.O浓度、光照强度等条件下M.O降解动力学。此外,纳米颗粒的可重用性方面也进行了研究,这表明,重复使用的纳米颗粒表现出相同的结果与原始颗粒。版权所有©2018 VBRI出版社。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Cu-ZnO nanoparticles for photocatalytic degradation of methyl orange
Photocatalytic degradation of textile dye derivative Methyl Orange (M.O) has been studied in aqueous medium using 2% copper doped zinc oxide (2% Cu-ZnO) nanoparticles under UV irradiation. Simple inexpensive chemical precipitation method was used for synthesis of pure and copper doped zinc oxide nanoparticles. The prepared nanoparticles pure and copper doped zinc oxide was characterized by X-ray Diffraction Technique (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis. The prepared nanoparticles were hexagonal wurzite structure. Photocatalytic efficiency of 2% Cu-ZnO were evaluated by studying mineralization of methyl orange (M.O.) as a model compound. The M.O. kinetics degradation was investigated under different parameters such as pH of the medium, catalyst dosage, M.O concentration, intensity of light etc. In addition reusability aspects of nanoparticles where also studied, which reveals that reused nanoparticles exhibited same results as that of virgin particles. Copyright © 2018 VBRI Press.
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