Natalya V. Lomova, Feodor F. Chausov, Lyudmila V. Dobysheva, A. I. Ul’yanov, Nikolay N. Zverev
{"title":"轻镧系元素(La - Tb)在不同结构的线性链硝基-三甲基-亚甲基膦酸盐中的磁性行为","authors":"Natalya V. Lomova, Feodor F. Chausov, Lyudmila V. Dobysheva, A. I. Ul’yanov, Nikolay N. Zverev","doi":"10.1002/pssb.202300278","DOIUrl":null,"url":null,"abstract":"The magnetic susceptibility is measured for two series of linear organic‐inorganic coordination polymers I‐Ln and II‐Ln (Ln = La–Tb). The structure of the polymers (isostructural in each series I‐Ln and II‐Ln) differs in the length and structure of the bridges and in the nearest environment of the lanthanides. The effective magnetic moments of lanthanide atoms are determined from the magnetic susceptibility. The measured magnetic moments agree with the values characteristic of isolated trivalent 3+ ions for all cases, except for Tb which demonstrates a higher value of 12.25 μB in one of the complexes. An analysis of the X‐ray photoelectron spectrum of Tb 5s makes it possible to estimate the spin magnetic moment of the Tb ion.This article is protected by copyright. All rights reserved.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":"10 1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magnetic Behavior of Light Lanthanide (La‐Tb) in Linear Chain Nitrilo‐Tris‐Methylene Phosphonates with Different Structures\",\"authors\":\"Natalya V. Lomova, Feodor F. Chausov, Lyudmila V. Dobysheva, A. I. Ul’yanov, Nikolay N. Zverev\",\"doi\":\"10.1002/pssb.202300278\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The magnetic susceptibility is measured for two series of linear organic‐inorganic coordination polymers I‐Ln and II‐Ln (Ln = La–Tb). The structure of the polymers (isostructural in each series I‐Ln and II‐Ln) differs in the length and structure of the bridges and in the nearest environment of the lanthanides. The effective magnetic moments of lanthanide atoms are determined from the magnetic susceptibility. The measured magnetic moments agree with the values characteristic of isolated trivalent 3+ ions for all cases, except for Tb which demonstrates a higher value of 12.25 μB in one of the complexes. An analysis of the X‐ray photoelectron spectrum of Tb 5s makes it possible to estimate the spin magnetic moment of the Tb ion.This article is protected by copyright. All rights reserved.\",\"PeriodicalId\":20107,\"journal\":{\"name\":\"physica status solidi (b)\",\"volume\":\"10 1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"physica status solidi (b)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/pssb.202300278\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"physica status solidi (b)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/pssb.202300278","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Magnetic Behavior of Light Lanthanide (La‐Tb) in Linear Chain Nitrilo‐Tris‐Methylene Phosphonates with Different Structures
The magnetic susceptibility is measured for two series of linear organic‐inorganic coordination polymers I‐Ln and II‐Ln (Ln = La–Tb). The structure of the polymers (isostructural in each series I‐Ln and II‐Ln) differs in the length and structure of the bridges and in the nearest environment of the lanthanides. The effective magnetic moments of lanthanide atoms are determined from the magnetic susceptibility. The measured magnetic moments agree with the values characteristic of isolated trivalent 3+ ions for all cases, except for Tb which demonstrates a higher value of 12.25 μB in one of the complexes. An analysis of the X‐ray photoelectron spectrum of Tb 5s makes it possible to estimate the spin magnetic moment of the Tb ion.This article is protected by copyright. All rights reserved.
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