经物理预处理的骆驼骨生物炭吸附Cd(II)和Pb(II

M. Rashed, A. A. Gad, Nada Magdy Fathy
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引用次数: 11

摘要

本研究采用物理处理法制备了低成本的骆驼骨生物炭吸附剂,并考察了所制备的骆驼骨生物炭对Cd2+和Pb2+的去除效果。采用XRD、SEM、FT-IR和BET表面对制备前后的生物炭吸附剂进行了表征,并对骨样品在500,600,800和900℃的温度下进行了热解。在pH、pH z、接触时间、初始金属浓度、吸附剂投加量和温度等条件下,对Pb和Cd的吸附效率进行了优化。通过吸附动力学、等温线和热力学模型对吸附技术进行了验证。结果表明,骆驼骨的有效热解温度为800℃,适合于高Cd和Pb的脱除。当接触时间为1 h、剂量为1 g、pH为5、初始金属浓度为10 mg/L时,对Cd和Pb的最大吸附去除率分别为99.4%和99.89%。吸附镉和铅的动力学结果符合拟二阶模型,符合Langmuir等温线。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adsorption of Cd(II) and Pb(II) Using Physically Pretreated Camel Bone Biochar
In this study low cost biochar adsorbent originated from camel bone was prepared by physically treatment, and examine the developed camel bone biochar for the removal of Cd2+ and Pb2+ from their solutions. The biochar adsorbent was characterized before and after development by XRD,SEM, FT-IR, and BET surface The bone sample was pyrolyzed at temperature 500,600, 800, and 900 °C. Adsorption efficiency of Pb and Cd were optimized at different parameters (pH,pH z, contact time , initial metal concentration , adsorbent dosage and temperature. Adsorption kinetic, isotherms, and thermodynamic models have been performed to confirm the adsorption technique.The results revealed that the effective pyrolysis temperature for camel bone was 800oC that suitable for the high removal of Cd and Pb.The maximum adsorption removal percentage for Cd and Pb were 99.4 and 99.89 % , respectively at constant contact time 1 h, 1 g dose, pH 5, and 10 mg/L intial metal concentration. The kinetic results of cadmium and lead adsorption obeyed a pseudo-second-order model and fitted well with the Langmuir isotherm.
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