电镀铜薄膜的显微组织对其机电可靠性的影响

Naokazu Murata, K. Tamakawa, K. Suzuki, H. Miura
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引用次数: 1

摘要

测定了镀铜薄膜在单轴应力作用下的静强度和疲劳强度。各膜的屈服应力、断裂伸长率和杨氏模量等力学性能由于其微观结构的不同而与体铜有较大差异。疲劳试验后用扫描电镜观察断口形貌。在疲劳试验中发现了两种断裂模式。一种是典型的韧性断裂,另一种是脆性断裂,即使在高于屈服应力的疲劳载荷下也是如此。由于在低于300℃的温度下退火后,初始显微织构发生了明显的变化,因此定量研究了电镀后热历史对其显微织构和疲劳强度的影响。除了力学性能外,薄膜的电学性能也因其微观结构的不同而有很大的不同。薄膜的电阻率远高于块状材料的电阻率,根据电镀条件的不同,电阻率的增加率从几到一百不等。这种增加也可归因于其微观结构的变化。在电迁移试验中,薄膜的断裂模式也发生了变化,从局部焦耳加热引起的局部熔合切割到铜原子扩散引起的常规电迁移。这种变化可以用薄膜的晶界特征来解释。当晶界相当多孔时,铜原子不能穿过相邻的晶粒。由于多孔晶界的电阻率非常高,由于高度局部化的焦耳加热,可能发生熔合切削。这种熔合切割在没有明显增加互连电阻的情况下意外发生。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of micro-texture of electroplated copper thin-films on their mechanical and electrical reliability
Both the static and fatigue strengths of electroplated copper thin films were measured under uni-axial stress. The mechanical properties such as the yield stress, fracture elongation and Young's modulus of each film were quite different from those of bulk copper depending on their micro structure. The fracture surfaces were observed by SEM after the fatigue test. It was found that there were two fracture modes under the fatigue test. One was a typical ductile fracture, and another was brittle one even under the fatigue load higher than its yield stress. Since the initial micro texture was found to change significantly even after the annealing at temperatures lower than 300°C, the effect of the thermal history of them after electroplating on both their micro texture and fatigue strength was investigated quantitatively. In addition to the mechanical properties, the electrical properties of the films varied significantly depending on their micro texture. The resistivity of the films was much higher than that of bulk material, and the increase ratio varied from a few to a hundred depending on the conditions of electroplating. This increase can be also attributed to the variation of their micro texture. The fracture mode of the films under electromigration tests also varied from the local fusion cutting caused by the localized Joule heating to the conventional electromigration caused by the diffusion of copper atoms. This change can be explained by the characterization of grain boundaries of the films. When the grain boundaries were rather porous, copper atoms could not cross the adjoining grains. Since the resistivity of the porous grain boundaries is very high, fusion cutting may occur due to the highly localized Joule heating. This fusion cutting occurs unexpectedly without clear increase of the resistance of interconnections.
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