Van der Waals epitaxial growth and optoelectronics of a vertical MoS2/WSe2 p-n junction.

Two-dimensional (2D) transition metal dichalcogenides (TMDs) have attracted extensive attention due to their unique electronic and optical properties. In particular, TMDs can be flexibly combined to form diverse vertical van der Waals (vdWs) heterostructures without the limitation of lattice matching, which creates vast opportunities for fundamental investigation of novel optoelectronic applications. Here, we report an atomically thin vertical p-n junction WSe₂/MoS₂ produced by a chemical vapor deposition method. Transmission electron microscopy and steady-state photoluminescence experiments reveal its high quality and excellent optical properties. Back gate field effect transistor (FET) constructed using this p-n junction exhibits bipolar behaviors and a mobility of 9 cm²/(V·s). In addition, the photodetector based on MoS₂/WSe₂ heterostructures displays outstanding optoelectronic properties (R = 8 A/W, D* = 2.93 × 10¹¹ Jones, on/off ratio of 10⁴), which benefited from the built-in electric field across the interface. The direct growth of TMDs p-n vertical heterostructures may offer a novel platform for future optoelectronic applications.