饱和氧铅铋共晶对双相Al 0.7CoCrFeNi高熵合金液态金属脆化的影响

Xing Gong, Congying Xiang, T. Auger, Jiajun Chen, Xiaocong Liang, Zhiyang Yu, M. Short, M. Song, Yuan Yin
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引用次数: 18

摘要

采用铅铋共晶(LBE)在350℃和500℃下对双相Al0.7CoCrFeNi(等摩尔分数)高熵合金(HEA)进行脆化处理,建立了一种新的液相金属脆化体系。在350℃时,富含(Ni, Al)的BCC相发生脆化,导致该相发生晶内开裂,而在500℃时,主要的开裂方式变为BCC/FCC相边界脱粘。在这两个温度下,富(Co, Cr, Fe)的FCC相很少出现裂纹,表明该相不受LME的影响。此外,结果表明,在350°C时,以吸附为主的LME机制转变为500°C时以相边界润湿为主的LME机制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Liquid Metal Embrittlement of a Dual-Phase Al 0.7CoCrFeNi High-Entropy Alloy Exposed to Oxygen-Saturated Lead-Bismuth Eutectic
Abstract This paper reports a new liquid metal embrittlement (LME) system in which a dual-phase Al0.7CoCrFeNi (equimolar fraction) high-entropy alloy (HEA) is embrittled by lead-bismuth eutectic (LBE) at 350 and 500°C. At 350°C, (Ni, Al)-rich BCC phase is embrittled, leading to intragrain cracking within this phase, while the predominant cracking mode changes to BCC/FCC phase boundary decohesion at 500°C. At both temperatures, cracks are rarely seen in the (Co, Cr, Fe)-rich FCC phase, indicating that this phase is immune to LME. Furthermore, the results suggest a transition from an adsorption-dominated LME mechanism at 350°C to a phase boundary wetting-dominated LME mechanism at 500°C.
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