水储存对纤维增强复合材料原始和修复粘结强度及残留单体释放的影响。

D. Wolff, Michael Coupek, R. Erber, T. Krueger, J. Krisam, H. Staehle, C. Frese
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引用次数: 3

摘要

目的探讨水储存对纤维增强复合材料(FRCs)剪切粘结强度(SBS)和单体释放的影响。材料与方法测试了四种单向FRCs,包括一种半互穿聚合物网络(IPN) (ES, everStick)和三种交联聚合物(CLP) FRCs (GT, GrandTec;TF, TenderFiber;DP Dentapreg)。在人工唾液中保存6个月和12个月后,评估具有完整氧抑制层的原始树脂(n = 30/组)和经过表面处理的修复树脂(n = 30/组)对新鲜FRC的SBS。采用高效液相色谱法检测树脂包覆和未包覆FRCs在浸泡1 h、1 d和7 d后单体释放情况。结果6个月后,es修复组SBS明显降低(p < 0.0001)。12个月后,ES-original (p < 0.0001)、ES-repair (p < 0.0001)和TF-repair (p = 0.0003)均显著降低。GT-original (p = 0.0254)和GT-repair (p = 0.0176)也显著降低。在6个月和12个月时,GT显示出最高的SBS值,dp -修复在12个月时与GT统计学上相似。对于UDMA和bis- GMA,未包覆的样品释放量最大,其次是可流动的树脂包覆和粘性树脂包覆的样品。结论基体组成、界面结合和树脂覆盖似乎是FRCs老化行为差异的原因。半ipn材料可能会受到最具挑战性的口腔条件的影响。中电财务汇报基金长期而言可能更稳定。强烈建议用粘性树脂覆盖FRCs,以减少残留单体的释放。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Aqueous Storage on Original and Repair Bond Strength and Residual Monomer Release of Fiberreinforced Composites.
PURPOSE To evaluate the effects of aqueous storage on shear bond strength (SBS) and monomer release of fiberreinforced composites (FRCs). MATERIALS AND METHODS Four unidirectional FRCs were tested, including one semi-interpenetrating polymer network (IPN) (ES, everStick) and three cross-linked polymer (CLP) FRCs (GT, GrandTec; TF, TenderFiber; DP, Dentapreg). The SBS of samples of original resin to fresh FRC with an intact oxygen inhibition layer (n = 30/group) and repair resin to FRC after surface treatment (n = 30/group) was evaluated after 6 and 12 months of storage in artificial saliva. Monomer release of polymerized resin-coated and uncoated FRCs was detected by high-performance liquid chromatography after immersion for 1 h, 1 day, and 7 days. RESULTS After 6 months, a significant decrease in SBS was seen with ES-repair (p < 0.0001). After 12 months, significant decreases were seen with ES-original (p < 0.0001), ES-repair (p < 0.0001), and TF-repair (p = 0.0003). A significant reduction was also found for GT-original (p = 0.0254) and GT-repair (p = 0.0176). At 6 and 12 months, GT showed the highest SBS values, with DP-repair being statistically similar to GT at 12 months. For UDMA and bis- GMA, the greatest amounts of release were seen in uncoated specimens, followed by flowable resin-coated and viscous resin-coated specimens. CONCLUSION Matrix composition, interfacial bonding, and resin coverage seem to account for differences in the aging behavior of FRCs. The semi-IPN material is likely to suffer most from the challenging oral conditions. CLP FRCs might be more stable over the long term. Coverage of FRCs with viscous resin is highly recommended to reduce residual monomer release.
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