{"title":"甲基丁醇:一个新的和简单的诊断工具，酸性和碱性的固体","authors":"H. Lauron-Pernot *, F. Luck, J.M. Popa","doi":"10.1016/0166-9834(91)80107-8","DOIUrl":null,"url":null,"abstract":"<div><p>In order to characterize acid-base properties of a material surface under gas-phase reaction conditions, a new test reaction has been investigated. We have shown that 2-methyl-3-butyn-2-oĺundergoes dehydration over solid acid materials and gives acetone and acetylene over solid basic materials. These reactions are very sensitive to the usual modifications that can occur during catalyst preparation. Production of 3-hydroxy-3-methyl-2-butanone seems to be characteristic of amphoteric catalysts possessing acid-base ion pairs.</p></div>","PeriodicalId":8091,"journal":{"name":"Applied Catalysis","volume":"78 2","pages":"Pages 213-225"},"PeriodicalIF":0.0000,"publicationDate":"1991-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-9834(91)80107-8","citationCount":"136","resultStr":"{\"title\":\"Methylbutynol: a new and simple diagnostic tool for acidic and basic sites of solids\",\"authors\":\"H. Lauron-Pernot *, F. Luck, J.M. Popa\",\"doi\":\"10.1016/0166-9834(91)80107-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In order to characterize acid-base properties of a material surface under gas-phase reaction conditions, a new test reaction has been investigated. We have shown that 2-methyl-3-butyn-2-oĺundergoes dehydration over solid acid materials and gives acetone and acetylene over solid basic materials. These reactions are very sensitive to the usual modifications that can occur during catalyst preparation. Production of 3-hydroxy-3-methyl-2-butanone seems to be characteristic of amphoteric catalysts possessing acid-base ion pairs.</p></div>\",\"PeriodicalId\":8091,\"journal\":{\"name\":\"Applied Catalysis\",\"volume\":\"78 2\",\"pages\":\"Pages 213-225\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1991-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0166-9834(91)80107-8\",\"citationCount\":\"136\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0166983491801078\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0166983491801078","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Methylbutynol: a new and simple diagnostic tool for acidic and basic sites of solids
In order to characterize acid-base properties of a material surface under gas-phase reaction conditions, a new test reaction has been investigated. We have shown that 2-methyl-3-butyn-2-oĺundergoes dehydration over solid acid materials and gives acetone and acetylene over solid basic materials. These reactions are very sensitive to the usual modifications that can occur during catalyst preparation. Production of 3-hydroxy-3-methyl-2-butanone seems to be characteristic of amphoteric catalysts possessing acid-base ion pairs.
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