{"title":"V/Cu/S异金属簇的合成及(Et 4 N) 2 [V 2 Cu 2 S 4 (C 5 H 10 dtc) 2 (PhS) 2 ]的结构表征","authors":"杨瑜黄梁仁吴达旭康北笙陈昌能邓玉恒卢嘉锡 刘秋田","doi":"10.1360/ZB1995-25-9-909","DOIUrl":null,"url":null,"abstract":"由(NH 4 ) 3 VS 4 ,CuCl,R 2 dtcNa和PhSNa组成的反应体系中,得到V 2 Cu 2 S 4 ,VS 4 Cu 4 及V 3 S 7 三种类型簇合物,讨论了产物形成过程。进行了(Et 4 N) 2 [V 2 Cu 2 S 4 (C 5 H 10 dtc) 2 (PhS) 2 ]的结构表征,确定了它的金属氧化态(Ⅴ(Ⅳ)+Cu(Ⅰ)),研究了它的红外及电子光谱、NMR谱及电化学循环伏安图。","PeriodicalId":21648,"journal":{"name":"Science in China. Series B, Chemistry, life sciences & earth sciences","volume":"17 1","pages":"909-915"},"PeriodicalIF":0.0000,"publicationDate":"1995-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"V/Cu/S异金属簇的合成及(Et 4 N) 2 [V 2 Cu 2 S 4 (C 5 H 10 dtc) 2 (PhS) 2 ]的结构表征\",\"authors\":\"杨瑜黄梁仁吴达旭康北笙陈昌能邓玉恒卢嘉锡 刘秋田\",\"doi\":\"10.1360/ZB1995-25-9-909\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"由(NH 4 ) 3 VS 4 ,CuCl,R 2 dtcNa和PhSNa组成的反应体系中,得到V 2 Cu 2 S 4 ,VS 4 Cu 4 及V 3 S 7 三种类型簇合物,讨论了产物形成过程。进行了(Et 4 N) 2 [V 2 Cu 2 S 4 (C 5 H 10 dtc) 2 (PhS) 2 ]的结构表征,确定了它的金属氧化态(Ⅴ(Ⅳ)+Cu(Ⅰ)),研究了它的红外及电子光谱、NMR谱及电化学循环伏安图。\",\"PeriodicalId\":21648,\"journal\":{\"name\":\"Science in China. Series B, Chemistry, life sciences & earth sciences\",\"volume\":\"17 1\",\"pages\":\"909-915\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science in China. Series B, Chemistry, life sciences & earth sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1360/ZB1995-25-9-909\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science in China. Series B, Chemistry, life sciences & earth sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1360/ZB1995-25-9-909","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
由(NH 4 ) 3 VS 4 ,CuCl,R 2 dtcNa和PhSNa组成的反应体系中,得到V 2 Cu 2 S 4 ,VS 4 Cu 4 及V 3 S 7 三种类型簇合物,讨论了产物形成过程。进行了(Et 4 N) 2 [V 2 Cu 2 S 4 (C 5 H 10 dtc) 2 (PhS) 2 ]的结构表征,确定了它的金属氧化态(Ⅴ(Ⅳ)+Cu(Ⅰ)),研究了它的红外及电子光谱、NMR谱及电化学循环伏安图。
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